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Tetrahedron: Asymmetry

Volumn 2, Issue 5, 1991, Pages 367-370

Preparation of optically active epoxides via sulfur ylides. Origin of the chiral induction.

(2) Breau, L a Durst, T a

a UNIVERSITY OF OTTAWA (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EPOXIDE; SULFUR DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; SYNTHESIS;

EID: 0025731654 PISSN: 09574166 EISSN: 1362511X Source Type: Journal
DOI: 10.1016/S0957-4166(00)82121-7 Document Type: Article

Times cited : (63)

References (23)

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8
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9
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10
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- An isomer of 3b, having the isopropyl group equatorial at C-4, has also been isolated in 7% yield.

11
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12
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- Such a conformation which results in considerable reduction of the steric interactions between the newly introduced substituents and the syn C-8 methyl group, compared to the chair conformation, is also supported by calculations using P.C. Model 4.0 (Still and Allinger) Babu C., private communication.

13
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23
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- that attack of the ylide on the carbonyl compound represents the rate-determining step in the epoxide formation.
- (1972) Tetrahedron Letters , pp. 3313
- Townsend¹ Sharpless²

* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.