메뉴 건너뛰기




Volumn 31, Issue 50, 1990, Pages 7333-7336

Catalytic asymmetric intramolecular hydrosilation

Author keywords

[No Author keywords available]

Indexed keywords

ALKANOL;

EID: 0025647455     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(00)88558-5     Document Type: Article
Times cited : (70)

References (28)
  • 8
    • 84918643167 scopus 로고    scopus 로고
    • 4a
  • 16
    • 84918612141 scopus 로고    scopus 로고
    • 3NCO, pyridine, toluene, 70 °C, 3 h, according to the Sumitomo direction. Similar derivatives of the minor anti [[Truncated]]
  • 17
    • 84918636929 scopus 로고    scopus 로고
    • 12 as ligand, but obtained rather low asymmetric induction (4 – 27 %ee) with both 2a (R Me) and 2b (RPh).
  • 19
    • 84941204901 scopus 로고
    • Catalytic, asymmetric, intermolecular hydrosilation of olefins and 1,3-dienes has been studied, but the highest optical yield ever reported was 66%. Review:, J.D. Morrison, Academic Press, New York
    • (1985) Asymmetric Synthesis , vol.5 , pp. 103
    • Ojima1    Hirai2
  • 22
    • 84918632270 scopus 로고    scopus 로고
    • 2, THF, DME, and benzene.
  • 23
    • 84918603301 scopus 로고    scopus 로고
    • − as catalyst the reaction of 2b proceeded rather fast (within 1 day at 30 °C) but with poor stereoselectivities (75% yield; 4, syn): anti = 94: 6; 4 26% ee).
  • 24
    • 0001479313 scopus 로고
    • A model for metal-templated catalytic asymmetric induction via .pi.-allyl fragments
    • While stereoselectivity has been shown to be improved by introduction of meta-substituted phenylphosphine ligands in certain intermolecular catalytic asymmetric synthesis, our present results suggest a similar effect on the substrate side in a catalytic intramolecular reaction.
    • (1985) Organometallics , vol.it4 , pp. 1143]
    • Trost1    Murphy2
  • 25
    • 84918614858 scopus 로고    scopus 로고
    • 2Si counterpart is now under investigation.
  • 28
    • 84918630122 scopus 로고    scopus 로고
    • We thank the Ministry of Education, Science, and Culture, Japan, for the Grant-in-Aid for Special Project Research (No. 01649005).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.