Dramatic enantioselectivity change in dihydroxylation of olefins with chiral amine-osmium tetroxide complex

Tetrahedron Letters

Volumn 31, Issue 12, 1990, Pages 1741-1742

  Tomioka, Kiyoshi ^a   Nakajima, Makoto ^a   Koga, Kenji ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

PYRROLIDINE DERIVATIVE;

ARTICLE; DRUG STRUCTURE; DRUG SYNTHESIS; NONHUMAN; PRIORITY JOURNAL; REACTION ANALYSIS;

EID: 0025255554     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(00)88869-3     Document Type: Article

References (18)

1. Asymmetric oxidation of olefins with osmium tetroxide coordinated by chiral diamines derived from L-tartaric acid.
2. A short asymmetric synthesis of anthracycline antibiotics
3. Enantioselective conjugate addition reaction mediated by chiral ligands.
4. Asymmetric .ALPHA.-alkylation of cyclohexanone by mediation of a chiral ligand and the leaving-group effect of electrophiles on enantioselectivity.
5. Novel strategy of using a C2 symmetric chiral diether in the enantioselective conjugate addition of an organolithium to an .alpha.,.beta.-unsaturated aldimine
6. Osmium tetraoxide cis hydroxylation of unsaturated substrates
7. Binding of alkenes to the ligands in OsO2X2 (X = O and NR) and CpCo(NO)2. A frontier orbital study of the formation of intermediates in the transition-metal-catalyzed synthesis of diols, amino alcohols, and diamines