Behavior of Singlet Molecular Oxygen (1ΔgO2) in a Polymer Matrix: Effects of Temperature, Matrix Rigidity, and Molecular Composition

Macromolecules

Volumn 22, Issue 9, 1989, Pages 3620-3628

  Clough, Roger L ^b   Dillon, Maria P ^a   Iu, Kai kong ^a   Ogilby, Peter R ^a  

^a UNIVERSITY OF NEW MEXICO   (United States)

^b SANDIA NATIONAL LABORATORIES   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COPOLYMERS--COMPOSITION EFFECTS; OXYGEN--PARTIAL PRESSURE SENSORS; PHOSPHORESCENCE--TEMPERATURE EFFECTS; POLYMETHYL METHACRYLATE--MOLECULAR STRUCTURE; POLYSTYRENES--MOLECULAR STRUCTURE;

FLASH ABSORPTION; MATRIX RIGIDITY EFFECTS; MOLECULAR COMPOSITION EFFECTS; POLYMER MATRIX; SINGLET MOLECULAR OXYGEN; TRIPLE STATE PHOTOSENSITIZER;

POLYMERS;

EID: 0024739212     PISSN: 00249297     EISSN: 15205835     Source Type: Journal    
DOI: 10.1021/ma00199a020     Document Type: Article

References (56)

1. Wasserman, H. H., Murray, R. W., Eds. Singlet Oxygen; Academic Press: New York, 1979.
2. Frimer, A. A., Ed. Singlet Oxygen; CRC Press: Boca Raton, FL, 1985.
3. Ranby, B.; Rabek, J. Singlet Oxygen: Reaction with Organic Compounds and Polymers; Wiley: New York, 1978.
4. Kaplan, M. L.; Trozzolo, A. M. In ref 1; pp 575–596.
5. Rabek, J. F. In ref 2, Vol. IV, pp 1–90.
6. Ogilby, P. R.; Iu, KK.; Clough, R. L. J. Am. Chem. Soc. 1987, 109, 4746–4747.
7. Clough, R. L.; Iu, K. K. ; Dillon, M. P.; Ogilby, P. R. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1988, 29, (1), 550–551.
8. Monroe, B. M. In ref 1, Vol. I.,pp 177–224 and references cited therein.
9. Iu, K. K. ; Ogilby, P. R. J. Phys. Chem. 1987, 91, 1611-1617. (b) Iu. K. K. ; Ogilby, P. R. J. Phys. Chem. 1988, 92. 5854.
10. Iu, K. K. ; Ogilby, P. R. J. Phys. Chem. 1988. 92. 4662–4666.
11. Gorman, A. A.; Rodgers, M. A. J. J. Am. Chem. Soc. 1986, 108, 5074–5078.
12. Schmidt, R.; Brauer, H. D. J. Am. Chem. Soc. 1987, 109, 6976–6981.
13. Scurlock, R. D.; Ogilby, P. R. J. Phys. Chem. 1987, 91, 4599–4602.
14. Iu, K. K. ; Scurlock, R. D.; Ogilby, P. R. J. Photochem. 1987, 37, 19–32.
15. West, M. A.; McCallum, K. J.; Woods, R. J.; Formosinho, S. J. Trans. Faraday Soc. 1970. 66. 2135–2147.
16. Ogilby, P. R. Ph.D. Dissertation, University of California—Los Angeles, 1981, Pp 33–35.
17. Ogilby, P. R.; Foote, C. S. J. Am. Chem. Soc. 1983, 105, 3423–3430.
18. Rogers, C. E. In Engineering Design for Plastics; Baer, E., Ed.; Reinhold: New York, 1964; P 647.
19. Haward, R. N., Ed. The Physics of Glassy Polymers; Wiley: New York, 1973; p 600.
20. Rodriguez, F. Principles of Polymer Systems; McGraw-Hill: New York, 1982; Pp 39–40.
21. Noe, L. J.; Degenkolb, E. O.; Rentzepis, P. M. J. Chem. Phys. 1978, 68, 4435–4438.
22. Hirata, Y.; Tanaka, I. Chem. Phys. Lett. 1976, 41, 336–338.
23. Kasama, K.; Kikuchi, K.; Uji-Ie, K.; Yamamoto, S. A. ; Kokubun, H. J. Phys. Chem. 1982, 86, 4733–4737.
24. Dobrowolski, D. C.; Ogilby, P. R.; Foote, C. S. J. Phys. Chem. 1983, 87, 2261–2263.
25. Geacintov, N.; Oster, G.; Cassen, T. J. Opt. Soc. Am. 1968, 58, 1217–1229.
26. Jansson, P. A. In Deconvolution; Jansson, P. A., Ed.; Academic Press: Orlando, FL, 1984; pp 1–34.
27. Demas, J. N. Excited State Lifetime Measurements; Academic Press: New York, 1983; Chapters 6 and 8.
28. Beswick, R. B.; Pitt, C. W. Chem. Phys. Lett. 1988, 143, 589–592.
29. Turro, N. J.; Cox, G. S., Li, X. Photochem. Photobiol. 1983, 37, 149–153.
30. Lee, E. D.; Werner, T. C.; Seitz, W. R. Anal. Chem. 1987, 59, 279–283.
31. Vieth, W. R.; Howell, J. M.; Hsieh, J. H. J. Membr. Sci. 1976, 1, 177–220.
32. Stannett, V. T. Polym. Eng. Sci. 1978, 18, 1129–1134.
33. Paul, D. R. Ber. Bunsenges. Phys. Chem. 1979, 83, 294–302.
34. Wayne, R. P. In ref 2, p 109.
35. Battino, R., Ed. IUPAC Solubility Data Series; Pergamon Press: Oxford, 1981; Vol. 7, Oxygen and Ozone.
36. Hormats, E. I.; Unterleitner, F. C. J. Phys. Chem. 1965, 69, 3677–3681.
37. Shaw, G. Trans. Faraday Soc. 1967, 63, 2181–2189.
38. Nowakowska, M.; Najbar, J.; Waligora, B. Eur. Polym. J. 1976, 12, 387–391.
39. Stannett, V. In Diffusion in Polymers; Crank, J., Park, G. S., Eds.; Academic Press: London, 1968; Pp 41–73.
40. Higashide, F.; Omata, K.; Nozawa, Y.; Yoshioka, H. J. Polym. Sci. 1977, 15, 2019–2028.
41. MacCallum, J. R.; Rudkin, A. L. Eur. Polym. J. 1978, 14, 655–656.
42. Guillet, J. Polymer Photophysics and Photochemistry; Cambridge University Press: Cambridge, 1985; p 56.
43. Hopfenberg, H. B.; Stannett, V. In The Physics of Glassy Polymers; Haward, R. N., Ed.; John Wiley: New York, 1973; pp 504–547.
44. Reference 52, pp 55–56, 195–209.
45. van Amerongen, G. Rubber Chem. Technol. 1964, 37, 1086–1089.
46. Mark, H. F.; Atlas, S. In Introduction to Polymer Science and Technology; Kaufman, S., Falcetta, J., Eds.; Wiley: New York, 1977; pp 22–23.
47. Somersall, A. C.; Dan, E.; Guillet, J. E. Macromolecules 1974, 7. 233–244.
48. Monnerie, L. In Polymer Photophysics; Phillips, D., Ed.; Chapman and Hall: London, 1985; pp 273–339 and references cited therein.
49. Rutherford, H.; Soutar, I. J. Polym. Sci. Polym. Phys. Ed. 1980, 18, 1021–1034.
50. McCrum, N. G.; Read, B. E.; Williams, G. Anelastic and Dielectric Effects in Polymeric Solids; John Wiley: London, 1967; Pp 238–299 and references cited therein.
51. North, A. M. In Molecular Behavior and The Development of Polymeric Materials; Ledwith, A., North, A. M., Eds.; Chapman and Hall: London, 1974; Pp 368–403.
52. Starkweather, H. W. Macromolecules 1981, 14, 1277–1281.
53. Manring, L. E.; Foote, C. S. J. Am. Chem. Soc. 1983, 105, 4710–4717.
54. Gorman, A. A.; Gould, I. R.; Hamblett, I. J. Am. Chem. Soc. 1982, 104, 7098–7104. (b) Gorman, A. A.; Gould, I. R.; Hamblett, I.: Standen. M. C. 1984. 106. 6956–6959.
55. Ogilby, P. R.; Foote, C. S. J. Am. Chem. Soc. 1981, 103, 1219–1221.
56. Bates, F. S.; Blair, H. E.; Hartnay, M. A. Macromolecules 1984, 17, 1987–1993.