Di- and Tetrafunctional Initiators for the Living Ring-Opening Olefin Metathesis Polymerization of Strained Cyclic Olefins

Macromolecules

Volumn 22, Issue 8, 1989, Pages 3205-3210

  Risse, Wilhelm ^a   Wheeler, David R ^a   Cannizzo, Louis F ^a   Grubbs, Robert H ^a  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

METALLORGANIC POLYMERS--MOLECULAR STRUCTURE; OLEFINS--POLYMERIZATION; ORGANOMETALLICS--POLYMERIZATION; POLYMERIZATION--CATALYSTS; TITANIUM COMPOUNDS--ORGANIC;

DIFUNCTIONAL INITIATORS; NORBORNENE LIVING ROMP; RING OPENING METATHESIS POLYMERIZATION (ROMP); STRAINED CYCLIC OLEFINS; TETRAFUNCTIONAL INITIATORS; TITANACYCLOBUTANE COMPOUND;

CATALYSTS;

EID: 0024716520     PISSN: 00249297     EISSN: 15205835     Source Type: Journal    
DOI: 10.1021/ma00198a003     Document Type: Article

References (16)

1. Gilliom, L. R.; Grubbs, R. H. J. Am. Chem. Soc. 1986,108, 733.
2. Reviews on olefin metathesis: (a) Dragutan, V.; Balaban, A. T.; Dimonie, M. Olefin Metathesis and Ring-Opening Polymerization of Cyclo-Olefins: Wiley-Interscience: Chichester, 1985. (b) Ivin, K. J. Olefin Metathesis; Academic Press: London, 1983). (c) Grubbs, R. H. In Comprehensive Organometallic Chemistry; Wilkinson, G., Ed.; Pergamon Press Ltd.: Oxford, 1982; Vol. 8, pp 499–551. (d) Banks, R. L. Catal. (London) 1981,4,100. (e) Basset, J. M.; Leconte, M. CHEMTECH 1980, 10, 762. (f) Katz, T. J.; Lee, S. J.; Shippey, M. A. J. Mol. Catal. 1980,8, 219. (g) Calderon, N. J. J. Macromol. Sci. Rev. 1972, C7 (1), 105.
3. Gilliom, L. R.; Grubbs, R. H. Organometallics 1986, 5, 721.
4. Arnold, D. R.; Trecker, J. D.; Whipple, E. B. J. Am. Chem. Soc. 1965, 87, 2596.
5. Tumas, W.; Wheeler, D. R.; Grubbs, R. H. J. Am. Chem. Soc. 1987. 109. 6182.
6. Jackman, L. M.; Sternhell, S. Applications of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry, 2nd. ed.; Pergamon Press: Oxford, 1969.
7. Review on hydrosilation: Speier, J. L. Adv. Organomet. Chem. 1979, 17, 407–447.
8. The preparation and characterization of the similar compound trimethylsilyl-3-bicyclo(2.2.1)heptene-5 is reported in: (a) Gassend, R.; Limouzin, Y.; Maire, J. C. Org. Magn. Reson. 1974, 6, 259. (b) Kuivila, H. G.; Warner, C. R. J. Org. Chem. 1964, 29, 2845.
9. Cannizzo, L. F.; Grubbs, R. H. Macromolecules 1987,20,1488.
10. Katz, T. L.; Lee, S. J. Acton, N. Tetrahedron Lett. 1976, 4247. (b) Katz, T., J.; Acton, N. Macromolecules 1976, 4251.
11. Risse, W.; Grubbs, R. H. submitted for publication in Macromolecules.
12. Martin, M. K.; Ward, T. C.; McGrath, J. E. In Anionic Polymerization; McGrath, J. E., Ed.; ACS Symposium Series 164; American Chemical Society: Washington DC., 1981.
13. Cannizzo. L. F.; Grubbs. R. H. Macromolecules 1988. 21. 1961.
14. Hall, L. D.; Sanders, J. K. M. J. Am. Chem. Soc. 1980, 102, 5703. Sanders, J. K. M.; Mersh, J. D. Prog. Nucl. Magn. Reson. Spectrosc. 1982, 15, 353.
15. Still. W. C.: Kahn. M.: Mitra, A. J. Org. Chem. 1978, 43, 2923.
16. Yau, W. W.; Kirkland, J. J.; Bly, D. D. Modern Size-Exclusion Chromatography; Wiley: New York, 1979.