A kinetic mathematical model for heterogeneous Ziegler-Natta copolymerization

Polymer

Volumn 30, Issue 2, 1989, Pages 280-296

  de Carvalho, A B ^a   Gloor, P E ^b   Hamielec, A E ^b  

^a Research and Development Department Polipropileno SA Polo Petroquimico do Nordeste Rua Hidrogenio s/n Camacari Bahia Brazil 42 810 ^*  (Brazil)

^b MCMASTER UNIVERSITY   (Canada)

Author keywords

copolymerization; gel permeation chromatography; kinetics; multiple site model; nuclear magnetic resonance; temperature rising elution fractionation; Ziegler Natta catalysts

Indexed keywords

CATALYSTS--ACTIVITY; CHROMATOGRAPHIC ANALYSIS--GEL PERMEATION; COMPUTERS--COMPUTATIONAL METHODS; MATHEMATICAL MODELS; POLYMERIZATION--CATALYSTS;

COPOLYMERIZATION KINETICS; HETEROGENEOUS ZIEGLER NATTA CATALYSTS; ISOSPECIFIC CATALYSTS; KINETIC MATHEMATICAL MODEL; ZIEGLER NATTA COPOLYMERIZATION;

OLEFINS;

EID: 0024611889     PISSN: 00323861     EISSN: None     Source Type: Journal    
DOI: 10.1016/0032-3861(89)90118-3     Document Type: Article

References (62)

1. The role of diffusion in propylene polymerization
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3. Molecular weight distribution and polymerization kinetics in some new catalytic processes
4. Continuous electron microscopic observation of the behavior of ziegler-natta catalysts
5. A uniform site theory of ziegler catalysis
6. The role of diffusion in the Ziegler polymerization of ethylene
7. Einfluß des stofftransportes bei der polymerisation von äthylen und 1-okten mit Ziegler-Katalysatoren
8. Fractional crystallization of polypropylene
9. The Fractionation of Polypropylene by Extraction with Boiling Hydrocarbons with Increasing Boiling Points