The chemistry of water treatment processes involving ozone, hydrogen peroxide and ultraviolet radiation

Ozone: Science & Engineering

Volumn 9, Issue 4, 1987, Pages 335-352

  Glaze, William H ^a   Kang, Joon Wun ^a   Chapin, Douglas H ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Advanced Oxidation Process Mechanisms; Chemistry; Hydrogen Peroxide; Hydroxyl Free Radicals; Ozone; Ozone Decomposition Products; Ozone H202; Ozone UV; Photolysis of Organic Compounds; Tetrachloroethylene Oxidation; Trichloroethylene Oxidation; Ultraviolet Radiation; Water Treatment Processes

Indexed keywords

HYDROGEN PEROXIDE - APPLICATIONS; OZONE - APPLICATIONS; ULTRAVIOLET RADIATION - APPLICATIONS;

HYDROXYL RADICAL GENERATION; OXIDATION MECHANISM; TREATMENT CHEMISTRY;

WATER TREATMENT;

EID: 0023537542     PISSN: 01919512     EISSN: 15476545     Source Type: Journal    
DOI: 10.1080/01919518708552148     Document Type: Article

References (45)

1. M. HORVATH; L. BILITZKY; J. HÜTTNER Ozone (Amsterdam, The Netherlands: Elsevier, 1985).
2. S. LALEZARY; M. PIRBAZARI; M.J. McGUIRE, “Oxidation of Five Earthy-Musty Taste and Odor Compounds”, J. Am. Water Works Assoc., 78 (3):62 (1986).
3. G.R. PEYTON; F.Y. HUANG; J.L. BURLESON; W.H. GLAZE, “Destruction of Pollutants in Water with Ozone in Combination with Ultraviolet Radiation. 1. General Principles and Oxidation of Tetrachloroethylene”, Environ. Sci. Technol. 16:448 (1982).
4. J. HOIGNE; H. BADER, “Rate Constants of Reactions of Ozone with Organic and Inorganic Compounds in Water. I. Non-Dissociating Organic Compounds”, Water Research, 17:173 (1983).
5. R.L. GARRISON; C.E. MAUK; H.W. PRENGLE, JR., “Advanced Ozone System for Complexed Cyanides”, in Proc. First International Symposium on Ozone for Water and Wastewater Treatment. R.G. Rice & M.E. Browning, Eds., (Norwalk, CT: International Ozone Assoc., 1975), p. 551.
6. H.W. PRENGLE, JR.; C.G. HEWES, III; C.E. MAUK, “Oxidation of Refractory Materials by Ozone with Ultraviolet Radiation”, in Proc. Second International Symposium _on_ Ozone Technology, R.G. Rice, P. Pichet & M.-A. Vincent, Eds., (Norwalk, CT: International Ozone Assoc., 1976), p. 224.
7. H.W. PRENGLE, JR.; C.E. MAUK, “Ozone/UV Oxidation of Pesticides in Aqueous Solution”, in Ozone/Chlorine Dioxide Oxidation Products of Organic Materials. R.G. Rice & J.A. Cotruvo, Eds., (Norwalk, CT: Intl. Ozone Assoc., 1978), p. 302.
8. H.W. PRENGLE, JR., “Evolution of the Ozone/UV Process for Wastewater Treatment”, Presented at IOI/EPA Colloquium on Wastewater Treatment & Disinfection with Ozone, U.S. Environmental Protection Agency, Municipal Environmental Research Laboratory, Cincinnati, OH, Sept. 15, 1977.
9. E. LEITLS; E.H. BRYAN; J.D. ZEFF; D.C. CROSBY; M. SMITH, “An Investigation into the Chemistry of the UV-Ozone Purification Process”, Presented at the 4th Ozone World Congress, Houston, Texas, November 27–29, 1979.
10. WESTGATE RESEARCH CORPORATION, “The Continued Investigation Into the Chemistry of the UV-Ozone Water Purification Process”, Proposal Submitted to National Science Foundation, February 28, 1978
11. J.D. Zeff, Private Communication.
12. W.H. GLAZE; G.R. PEYTON; F.Y. HUANG; J.L. BURLESON; P.C. JONES, “Oxidation of Water Supply Refractory Species by Ozone and Ultraviolet Radiation”, EPA Report No. EPA-600/2-80-110, (Cincinnati, OH: U.S. Environmental Protection Agency, Municipal Environmental Research Laboratory, August, 1980).
13. W.H. GLAZE; G.R. PEYTON; S. LIN; F.Y. HUANG; J.L. BURLESON, “Destruction of Pollutants in Water with Ozone in Combination with Ultraviolet Radiation. 2. Natural Trihalomethane Precursors”, Environ. Sci. Technol. 16:454 (1982).
14. PEYTON, G.R.; W.H. GLAZE, “Mechanism of Photolytic Ozonation”, in Photochemistry__of_Environmental Aquatic Systems, R.G. Zika & W.J. Cooper, Eds., ACS Symposium Series 327, (Washington, DC: Am. Chem. Soc., 1986), pp. 76–88.
15. M.K. LEE; G.G. SEE; R.A. WYNVEEN, “Reaction Kinetics of UV/Ozone with Organic Compounds in Hospital Wastewater”, Presented at the Symposium on Advanced Ozone Technology, International Ozone Institute, Toronto, Ontario, Canada, Nov. 16–18, 1977.
16. E.S.K. CHIAN; P.P.K. KUO, “Fundamental Study of the Post-Treatment of RO Permeates from Army Wastewaters”, Second Annual Summary Report to U.S. Army Medical Research and Development Command, Contract No. DAMD 17-75-C-5506, 1976.
17. P.P.K. KUO; E.S.K. CHIAN; B.J. CHENG, “Identification of End Products Resulting from Ozonation of Compounds Commonly Found in Water”, in Ozone/Chlorine Dioxide Oxidation Products of Organic Materials, R.G. Rice & J.A. Cotruvo, Eds., (Norwalk, CT: Intl. Ozone Assoc., 1978), p. 153.
18. E.G. FOCHTMAN; J.E. HUFF, “Ozone-Ultraviolet Light Treatment of TNT Wastewaters”, in Proc. Second International. Symposium on Ozone Technology, R.G, Rice, P. Pichet & M.-A. Vincent, Eds., (Norwalk, CT: International Ozone Assoc., 1976), p. 211.
19. W.H. GLAZE; G.R. PEYTON; B. SOHM, “Pilot Scale Evaluation of Photolytic Ozonation for Trihalomethane Precursor Removal”, Report of Cooperative Agreement CR-808825, U.S. Environmental Protection Agency, Municipal Environmental Research Laboratory, Cincinnati, OH., June, 1984.
20. F.C. FARRELL; J.D. ZEFF; T.C. CRASE; D.T. BOYLAND, “Development Effort to Design and Describe Pink Water Abatement Processes”, Final. Technol. Report No 1701 to U.S. Army Armament R&D Command, Dover, NJ, August, 1977.
21. S. NAKAYAMA; K. ESAKI; K. NAMBA; Y. TANIGUCHI; N. TABATA, “Improved Ozonation in Aqueous Systems”, Ozone Sci. & Engrg. 1:119 (1979).
22. R.A. HANGO; L.J. BOLLYKY; F. DOANE, “Wastewater Treatment for Re-Use in Integrated Circuit Manufacturing”, in Wasser Berlin 181, 5. Ozon Weltkongress. (Berlin, Federal Republic of Germany: Colloquium Verlag, Otto H. Hess, 1981), p. 304.
23. L.J. BOLLYKY, “Pilot Plant Studies for THM, Taste and Odor Control Using Ozone and Ozone-Hydrogen Peroxide”, in The Role of Ozone in Water and Wastewater Treatment, Proceedings of the Second International Conference, D.W. Smith & G.R. Finch, Eds. (Kitchener, Ontario, Canada: Tek Tran International, Inc., 1987), p. 211.
24. R. BRUNET; M.M. BOURBIGOT; M. DORE, “Oxidation of Organic Compounds Through the Combination Ozone-Hydrogen Peroxide”, Ozone Sci. & Engrg., 6:163 (1984).
25. J.P. DUGUET; E. BRODARD; B. DUSSERT; J. MALLEVIALLE, “Improvement in the Effectiveness of Ozonation of Drinking Water Through the Use of Hydrogen Peroxide”, Ozone Sci. & Engrg. 7:241 (1985).
26. W.H. GLAZE; J.-W. KANG; E.M. AIETA, “Ozone-Hydrogen Peroxide Systems for Control-of Organics in Municipal Water Supplies”, in The. Role _of Ozone in Water and Wastewater. Treatment. _Proceedings of_the Second International Conference, D.W. Smith & G.R. Finch, Eds. (Kitchener, Ontario, Canada: Tek Tran International, Inc., 1987), p. 233.
27. L. BERGLIND; E. GJESING; E. SKIPPERUD JOHANSEN, “Removal of Organic Matter in Water by UV and Hydrogen Peroxide”. In Oxidation Techniques in_Drinking Water Treatment, W. Kühn & H. Sontheimer, Eds., U.S. EPA, Report No. EPA-570/9-79-020, (Washington, DC: U.S. Environmental Protection Agency, Office of Drinking Water, 1979), pp. 510–523.
28. E. KOUBECK, “Oxidation of Refractory Organics in Aqueous Waste Streams by Hydrogen Peroxide and Ultraviolet Light”, U.S. Patent No. 4, 012, 321 (1977).
29. J. WEISS, “The Radical ho2 in Solution”, Trans. Faraday Soc., 31:668 (1935).
30. J. HOIGNE; H. BADER, “Ozonation of Water: Role of Hydroxyl Radicals as Oxidizing Intermediates”, Science, 109:4216 (1975).
31. J. STAEHELIN; J. HOIGNE, “Decomposition of Ozone in Water: Rate of Initiation by Hydroxide Ion and Hydrogen Peroxide”, Environ. Sci. & Technol., 16:676 (1982).
32. R.E. BÜHLER; J. STAEHELIN; J. HOIGNE, “Ozone Decomposition in Water Studied by Pulse Radiolysis. 1. H02/02 and HO3/O3 as Intermediates', J. Phys. Chem., 88:2560 (1984).
33. J. STAEHELIN; R.E. BÜHLER; J. HOIGNE, “Ozone Decomposition in Water Studied by Pulse Radiolysis. 2. OH and H0n as Chain Intermediates”, J. Phys. Chem., 88:5999 (1984).
34. L. FORNI; D. BAHNEMANN; E.J. HART, “Mechanism of the Hydroxide Ion Initiated Decomposition of Ozone in Aqueous Solution”, J. Phys. Chem., 86:255 (1982).
35. K. SEHESTED; J. HOLOMAN; E. BJERGBAKKE; E.J. HART, “Ultraviolet Spectrum and Decay of the Ozonide Ion Radical, 03, in Strong Alkaline Solution”, J. Phys. Chem., 86:2066 (1982).
36. J. STAEHELIN; J. HOIGNE, “Decomposition of ozone in the Presence of Organic Solutes Acting as Promoters and Inhibitors of Radical Chain Reactions”, Environ. Sci. & Technol., 19:1206 (1985).
37. J. HOIGNE; H. BADER, “Ozone Hydroxyl Radical-Induced Oxidations of Organic and Organometallic Trace Impurities in Water”, in Organometals and Organometalloids: Occurrence and Fate in_the Environment, R.R. Brinckman & J.M. Bellama, Eds., ACS Symposium Series 82, (Washington, DC: American Chemical Society, 1978), pp. 292–313.
38. J.M. SYMONS et al., Treatment Techniques for. Controlling Trihalomethanes in Drinking Water, U.S. EPA Report No. EPA-600/2-81-156, (Cincinnati, OH: U.S. Environmental Protection Agency, Drinking Water Research Division, September, 1981), pp. 125–128.
39. B. LEGUBE; J.P. CROUE; D.A. RECKHOW; M. DORE, “Ozonation of Organic Precursors: Effects of Bicarbonate and Bromide”, in Proceedings of_the International Conference, on The_Role of Ozone in Water and Wastewater Treatment, R. Perry & A.E. McIntyre, Eds., (London, England: Selper Ltd, 1985), pp. 73–86.
40. H.S. CHRISTENSEN; K. SEHESTED; H. CORFITZAN, “Reactions of Hydroxyl Radicals with Hydrogen Peroxide at Ambient and Elevated Temperatures”, J. Phys. Chem., 86:1588 (1982).
41. E.M. AIETA, James M. Montgomery, Consulting Engineers, Pasadena, CA (Personal Communication).
42. H. OKABE, Photochemistry of Small Molecules, (New York, NY: Wiley Interscience, 1978), p. 244.
43. H. TAUBE, “Photochemical Reactions of Ozone in Solution”, Trans. Faraday Soc., 53:656 (1957).
44. J.H. BAXENDALE; J.A. WILSON, “The Photolysis of Hydrogen Peroxide at High Light Intensities”, Trans. Faraday Soc., 53:344 (1957).
45. A.L. LAZRUS; G.L. KOK; S.N. GITLIN; J.A. LIND; S.E. McLAREN, “Automated Fluorometric Method for Hydrogen Peroxide in Atmospheric Precipitation”, Anal. Chem. 57: 917–922 (1985).