The mechanism of phosphine-modified rhodium-catalyzed hydroformylation studied by CIR-FTIR

Journal of Molecular Catalysis

Volumn 41, Issue 3, 1987, Pages 271-292

  Moser, William R ^a   Papile, Christopher J ^a   Brannon, David A ^a   Duwell, Ronald A ^a   Weininger, Stephen J ^a  

^a WORCESTER POLYTECHNIC INSTITUTE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDES - CHEMICAL REACTIONS; AROMATIC COMPOUNDS - SYNTHESIS; CATALYSIS; CHEMICAL REACTIONS - REACTION KINETICS; SPECTROSCOPY, INFRARED - APPLICATIONS;

1-HEXENE; HYDROFORMYLATION; PHOSPHINE-MODIFIED RHODIUM CATALYST;

CATALYSTS;

EID: 0023389515     PISSN: 03045102     EISSN: None     Source Type: Journal    
DOI: 10.1016/0304-5102(87)80106-2     Document Type: Article

References (30)

1. Oxo Alcohols
2. RECENT DEVELOPMENTS IN HYDROFORMYLATION CATALYSIS
3. Addition reactions of tris(triphenylphosphine)chlororhodium(I); hydrido-, alkyl, and acyl complexes; carbon monoxide insertion and decarbonylation reactions
4. The reaction of hydridocarbonyltris(triphenylphosphine)rhodium with carbon monoxide, and of the reaction products, hydridodicarbonylbis(triphenylphosphine)rhodium and dimeric species, with hydrogen
5. Hydroformylation of alkenes by use of rhodium complex catalysts
6. Homogeneous hydroformylation of alkenes with hydridocarbonyltris-(triphenylphosphine)rhodium(I) as catalyst.
7. Further studies on hydridocarbonyltris(triphenylphosphine)rhodium(I); intermediate species in hydroformylation; rhodium and iridium analogues
8. HYDROFORMYLATION OF OLEFINS WITH RHODIUM CARBONYLS AS CATALYSTS. IV. MECHANISM OF THE REACTION
9. The oxidative addition of iodomethane to trans-halogenocarbonylbis(triarylphosphine)rhodium(I) and the subsequent isomerisation via methyl transfer to an acetyl complex
10. Further studies on hydridocarbonyltris(triphenylphosphine)rhodium(I). Part I. Nature of inactivation of catalytic reactions