Stereoselective reduction of C-2 substituted steroid C-3 ketones with lithium tris-(R,S-1,2-dimethylpropyl)-borohydride and sodium borohydride

Steroids

Volumn 48, Issue 5-6, 1986, Pages 339-346

  Templeton, John F ^a   Kumar, V P Sashi ^a   Gupta, R K ^a   Friesen, Anne M ^a  

^a UNIVERSITY OF MANITOBA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

OXOSTEROID;

DIBORANE; REDUCTION; STEREOCHEMISTRY;

BOROHYDRIDES; CHEMISTRY; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; LITHIUM; MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION-REDUCTION; STEREOISOMERISM; STEROIDS; SUPPORT, NON-U.S. GOV'T;

EID: 0022944528     PISSN: 0039128X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0039-128X(86)90020-6     Document Type: Article

References (22)

1. Stereoselective and regioselective reduction of steroid ketones by potassium tri(R,S-s-butyl) borohydride
2. J Chem Soc (C)
3. Desulfuration Experiments with 1,3-Oxathiolan-5-ones
4. Rapid Stereospecific Methylation of Alcohols and Glycols with Sodium Hydride/Methyl Iodide1
5. 13. Researches on acetylenic compounds. Part I. The preparation of acetylenic ketones by oxidation of acetylenic carbinols and glycols
6. C-3 to C-2 Carbonyl Transposition via a Vinyl Chloride in Ring-A of Steroids
7. The Partial Synthesis of 12α-Methyl-11-dehydrocorticosterone
8. Acetalisierungsreaktionen an Steroidketonen; ein neues Verfahren zur Darstellung von Testosteron und Dihydrotestosteron