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Volumn 25, Issue 6, 1986, Pages 487-507

Second‐Sphere Coordination–a Novel Rǒle for Molecular Receptors

Author keywords

Coordination modes; Receptors; Second sphere coordination; Supramolecular chemistry

Indexed keywords

ALPHA CYCLODEXTRIN; AMMONIA; BETA CYCLODEXTRIN; BORANE DERIVATIVE; CISPLATIN; CROWN ETHER; GAMMA CYCLODEXTRIN; LASALOCID; METAL; PLATINUM DERIVATIVE; RHODIUM COMPLEX;

EID: 0022523376     PISSN: 05700833     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.198604873     Document Type: Review
Times cited : (250)

References (170)
  • 6
    • 84985599417 scopus 로고    scopus 로고
    • Cyclodextrins and their Inclusion Complexes, Akademiai Kiado 1982
    • Szejtli, J.1
  • 8
    • 0003815301 scopus 로고
    • J. L. Atwood, J. E. D. Davies, D. D. MacNicol, Academic Press, London
    • (1984) Inclusion Compounds , vol.1-3
  • 49
    • 84985539465 scopus 로고    scopus 로고
    • Second‐sphere coordination of transition metal complexes affords complexes of complexes. We find it convenient to refer to these complexes of complexes as adducts.
  • 57
    • 84985509361 scopus 로고    scopus 로고
    • 2], synthesized by Chatt's Research Group working at The Frythe (ICI) some 25 years earlier!
  • 64
    • 84985595732 scopus 로고    scopus 로고
    • unpublished, also form 2:1 complexes provided the formal positive charge is not directly associated with the binding group (e. g. [{Ph3PMe}} 2 · 18C6]¶PF62, [{Ph2SMe}2 · 18C6¶Hg2I6] and [{PhCOCHPhSMe2}2 · 18C6¶PF6]2). The bireceptor nature of 18C6 manifests itself structurally in yet another manner. Neutral (e.g. MeO2CCCCO2Me) and cationic (e.g. [PhCOCH2SMe2]⊕) organic molecules containing two binding groups can form polymeric hydrogen bonded structures with alternating 18C6 units.
    • Pears, D.A.1    Stoddart, J.F.2    Crosby, J.3    Allwood, B.L.4    Williams, D.J.5
  • 161
    • 0037717347 scopus 로고
    • The stereoselective retardation of the alkaline hydrolysis of organic esters by binuclear Cu(II) complexes with cyclodextrins.
    • is supported subsequently by firm structural evidence, then it could constitute an interesting example of simultaneous first‐ and second‐sphere coordination of copper(II) by α‐CD
    • (1985) Bulletin of the Chemical Society of Japan , vol.58 , pp. 1658
    • Matsui, Y.1    Suemitsu, D.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.