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The energy difference for the differently substituted ions is only 12.9 kcal/mol with MINDO/3 still favoring the aminodiazonium ion. A similar energy variation between ab initio 4-31G and MINDO/3 has been calculated for the C- vs. N-protonation of diazomethane.26
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The energy difference for the differently substituted ions is only 12.9 kcal/mol with MINDO/3 still favoring the aminodiazonium ion. A similar energy variation between ab initio 4-31G and MINDO/3 has been calculated for the C- vs. N-protonation of diazomethane.26
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