Synthesis of Inequivalently Bridged Cyclopentadienyl Dimers of Molybdenum and a Comparison of Their Reactivities with Unsaturated Molecules and with Hydrogen

Journal of the American Chemical Society

Volumn 105, Issue 16, 1983, Pages 5329-5337

  McKenna, Maryanne ^a   Wright, Laura L ^a   Miller, Douglas J ^a   Tanner, Linnea ^a   Haltiwanger, R C ^a   DuBois, M Rakowski ^a  

^a UNIVERSITY OF COLORADO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN;

MOLYBDENUM COMPOUNDS;

EID: 0020798935     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00354a024     Document Type: Article

References (35)

1. Alfred P. Sloan Research Fellow, 1981-1983. Camille and Henry Dreyfus Teacher Scholar, 1981-1986.
2. Rakowski DuBois, M.; VanDerveer, M.C.; DuBois, D.L.; Haltiwanger, R.C.; Miller, W.K. J. Am. Chem. Soc. 1980, 102, 7456.
3. Rakowski DuBois, M.; DuBois, D.L.; VanDerveer, M.C.; Haltiwanger, R.C. Inorg. Chem. 1981, 20, 3064.
4. Miller, D.J.; Haltiwanger, R.C.; Rakowski DuBois, M. “Proceedings of 4th International Conference on the Chemistry and Uses of Molybdenum”; Barry, H.F., Ed.; Climax Molybdenum Co.: Ann Arbor, MI, 1982; p. 384.
5. Rakowski DuBois, M.; Haltiwanger, R.C.; Miller, D.J.; Glatzmeier, G. J. Am. Chem. Soc. 1979, 101, 5245.
6. Dyer, J.R. “Applications of Absorption Spectroscopy of Organic Compounds”; Prentice-Hall: Englewood Cliffs, NJ, 1965; p. 99.
7. Reference 6, p. 74.
8. DuBois, D.L.; Miller, W.K.; Rakowski DuBois, M. J. Am. Chem. Soc. 1981, 103, 3429.
9. Hirobe, M.; Nagano, T. Tetrahedron Lett. 1980, 21, 1343.
10. Muetterties, E.L.; Slater, S. Inorg. Chem. 1980, 19, 3337.
11. Osborn, J.A.; Schrock, R.R. J. Am. Chem. Soc. 1976, 98, 2143.
12. Muetterties, E.L.; Hirsekorn, F.J.; Beier, B.F.; Pretzer, W.R.; Thomas, M.G. J. Am. Chem. Soc. 1977, 99, 743.
13. Lindlar, H.; Gutmann, H. In “Acetylenes”; Marcel Dekker: New York, 1969; Chapter 6.
14. Stiefel, E.I.; Newton, W.E.; Watt, G.D.; Hadfield, K.L.; Bulen, W.A. Adv. Chem. Ser. 1977, No. 162, 353.
15. Lacey, R.N. In “The Chemistry of Alkenes”; Patai, S., Ed.; Wiley: New York, 1964; p. 1173.
16. Hardy, R.W.F.; Burns, R.C.; Parshall, G.W. Adv. Chem. Ser. 1971, No. 100, 219.
17. Bowden, F.L.; Giles, R. Coord. Chem. Rev. 1976, 20, 81.
18. Dyke, A.F.; Knox, S.A.R.; Naish, P.J. J. Organomet. Chem. 1980, 199, C47.
19. Herrmann, W.A.; Plank, J. Angew. Chem., Int. Ed. Engl. 1978, 17, 525.
20. McKenna, M.; Casewit, C.; Rakowski DuBois, M., manuscript in preparation.
21. Casewit, C.; Rakowski DuBois, M., unpublished results.
22. Miller, W.K.; Haltiwanger, R.C.; VanDerveer, M.C.; Rakowski DuBois, M. Inorg. Chem., in press.
23. Connelly, N.G.; Dahl, L.F. J. Am. Chem. Soc. 1970, 92, 7470.
24. Shaver, A.; Fitzpatrick, P.J.; Steliou, K.; Butler, I.S. J. Am. Chem. Soc. 1979, 101, 1313.
25. Davies, C.G.; Gillespie, R.J.; Park, J.J.; Passmore, J. Inorg. Chem. 1971, 10, 2781.
26. Eisenberg, R.; Steifel, E.I.; Rosenberg, R.C.; Gray, H.B.J. Am. Chem. Soc. 1966, 88, 2874.
27. King, R.B. “Organometallic Syntheses”; Academic Press: New York, 1965; Vol. 1, p. 109.
28. Williams, J.W.; Hurd, C.D. J. Org. Chem. 1940, 5, 122.
29. Taylor, E.C.; McKillop, A.; Hawks, G.H. Org. Synth. 1972, 52, 36.
30. Main, P. “MULTAN 78. A System of Computer Programs for the Automatic Solution of Crystal Structures”; Department of Physics, University of York, York, England, March, 1978; obtained from Dr. Grahame, J.D. Williams, Brookhaven National Laboratory, Upton, NY.
31. Wenzel, T.J.; Sievers, R.E. Anal. Chem. 1981, 53, 393.
32. Carey, F.A.; Court, A.S. J. Org. Chem. 1972, 37, 1926.
33. Bornstein, J.; Joseph, M.A.; Shields, J.E. J. Am. Chem. Soc. 1965, 30, 801.
34. “The Sadtler Standard Spectra”; Sadtler Research Laboratories, Inc.: Philadelphia, PA, 1976.
35. Busing, W.R.; Levy, H.A. J. Chem. Phys. 1957, 26, 563; Corfield, P.W.R.; Doedens, R.J.; Ibers, J.A. Inorg. Chem. 1967, 6, 197.