Chemical Reaction Paths. 8. Stereoisomerization Path for Triphenylphosphine Oxide and Related Molecules: Indirect Observation of the Structure of the Transition State

Journal of the American Chemical Society

Volumn 104, Issue 22, 1982, Pages 5893-5898

  Bye, Erik ^a   Schweizer, W Bernd ^a   Dunitz, Jack D ^a  

^a ETH ZURICH   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL REACTIONS;

EID: 0020474315     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00386a008     Document Type: Article

References (7)

1. Part 7. Britton, D.; Dunitz, J. D. J. Am. Chem. Soc. 1981, 103, 2971–2979.
2. Bürgi, H. B. Inorg. Chem. 1973, 12, 2321–2325.
3. Murray-Rust, P.; Bürgi, H. B.; Dunitz, J. D. J. Am. Chem. Soc. 1975, 97, 921–922.
4. Dunitz, J. D. “X-Ray Analysis and the Structure of Organic Molecules”; Cornell University Press: Ithaca, NY, 1979; Chapter 7.
5. Murray-Rust, P.; Bürgi, H. B.; Dunitz, J. D. Acta Crystallogr., Sect. A 1979, 35, 703–713.
6. Andose, J. D.; Mislow, K. J. Am. Chem. Soc. 1974, 96, 2168–2176.
7. The two-ring flip mechanism is also indicated by dynamic NMR studies of variously substituted triarylboranes, triarylmethanes, and cognate molecules in solution. See K. Mislow, Acc. Chem. Res. 1976, 9, 26–33, for a review of the experimental evidence and its interpretation.