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Volumn 42, Issue 5, 1982, Pages 365-368

X-ray absorption spectra: K-edges of 3d transition metals, L-edges of 3d and 4d metals, and M-edges of palladium

Author keywords

[No Author keywords available]

Indexed keywords

PALLADIUM AND ALLOYS;

EID: 0020126960     PISSN: 00381098     EISSN: None     Source Type: Journal    
DOI: 10.1016/0038-1098(82)90154-5     Document Type: Article
Times cited : (356)

References (14)
  • 4
    • 84918080708 scopus 로고    scopus 로고
    • J.E. Müller and J.W. Wilkins, to be published.
  • 6
    • 84918080707 scopus 로고    scopus 로고
    • We have used a non-self-consistent potential, constructed according to the scheme of
  • 7
    • 36149028300 scopus 로고
    • In the case of Pd, the spectra calculated with a self-consistent potential (graciously supplied by D. Glötzel) showed discrepancies of a few eV only in the low energy part.
    • (1964) Phys. Rev. , vol.133 , pp. A1399
    • Mattheiss1
  • 8
    • 84918080706 scopus 로고    scopus 로고
    • The core-hole widths in Table 1 represent our best estimates from the compilations of
  • 11
    • 84918080705 scopus 로고    scopus 로고
    • x(E) in Fig. 1 is our best estimate from the compilation of
  • 13
    • 84918080704 scopus 로고    scopus 로고
    • −1(E)
  • 14
    • 84918080703 scopus 로고    scopus 로고
    • Note the similarities of scaled spectra (above ∼20 eV) for fcc (Ca and Cu) and hcp elements (Ti and Co). That the high energy structure is so similar for both fcc and hcp (with nearly ideal c/a ratios) is evidence that the spectrum is increasingly dominated by the number and distances of the nearest neighbors. The relatively flat spectrum of Zn (with a non-ideal c/a ratio) results from interference of peaks due to two sets of nearest-neighbor atoms at different distances from the excited atom.


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