The Crystal Structure and Molecular Stereochemistry of μ-Oxo-bis[α,β,γ,δ-tetraphenylporphinatoironCIII)]

Journal of the American Chemical Society

Volumn 94, Issue 10, 1972, Pages 3620-3626

  Hoffman, A B ^a,b   Collins, D M ^a,b   Day, V W ^a,b   Fleischer, E B ^a,b   Snvastava, T S ^a,b   Hoard, J L ^a,b  

^a Department of Obstetrics Gynecology   (United States)

^b UNIVERSITY OF CHICAGO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

IRON; PORPHYRIN;

ARTICLE; CRYSTALLOGRAPHY; DENSITOMETRY; MOLECULAR WEIGHT;

CRYSTALLOGRAPHY; DENSITOMETRY; IRON; MOLECULAR WEIGHT; PORPHYRINS;

EID: 0015513712     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00765a060     Document Type: Article

References (30)

1. D. F. Koenig, Acta Crystallogr., 18, 663 (1965).
2. J. L. Hoard, M. J. Hamor, T. A. Hamor, and W. S. Caughey, I.Amer. Chem. Soc, 87, 2312 (1965).
3. J. L. Hoard, G. H. Cohen, and M. D. Click, I.Amer. Chem. Soc, 89, 1992 (1967).
4. C. Maricondi, W. Swift, and D. K. Straub, J. Amer. Chem. Soc, 91, 5205 (1969)
5. cf. P. L. Richards, W. S. Caughey, H. Eberspaecher, G. Feher, and M. Malley, J. Chem.Phys., 47, 1187 (1967).
6. E. B. Fleischer and T. S. Srivastava, J. Amer. Chem. Soc, 91, 2403 (1969).
7. I. A. Cohen, J. Amer. Chem. Soc, 91, 1980 (1969).
8. L. H. Vogt, Jr., A. Zalkin, and D. H. Templeton, Inorg. Chem., 6, 1725 (1967).
9. S. J. Lippard, H. Schugar, and C. Walling, Inorg. Chem., 6, 1825 (1967).
10. “International Tables for X-Ray Crystallography. Vol. I. Symmetry Groups,” Kynoch Press, Birmingham, England, 1952, p 127.
11. Following W. R. Busing, K. O. Martin, and H. A. Levy, “OR-FLS, a Fortran Crystallographic Least-Squares Program,” ORNL-TM-305, Oak Ridge National Laboratory, Oak Ridge, Tenn., 1962.
12. Atomic form factors were from D. T. Cromer and J. L. Mann, Acta Crystallogr., Sect. A, 24, 321 (1968)
13. corrections for anomalous scattering were from D. T. Cromer, Acta Crystallogr., Sect. A, 18, 17 (1965).
14. V. W. Day and J. L. Hoard, J. Amer. Chem. Soc, 92, 3626 (1970).
15. D. M. Collins and J. L. Hoard, J. Amer. Chem. Soc, 92, 3761 (1970).
16. L. J. Radonovich, A. Bloom, and J. L. Hoard, J. Amer. Chem. Soc, 94, 2073 (1972).
17. D. M. Collins, W. R. Scheldt, and J. L. Hoard, J. Amer. Chem. Soc, submitted for publication.
18. Cf. J. L. Hoard in “Structural Chemistry and Molecular Biology,” A. Rich and N. Davidson, Ed., W. H. Freeman, San Francisco, Calif. 1968, pp 573-594, and references cited therein.
19. The structure reported as that of (HOFeOHTPP [E. B. Fleischer, C. K. Miller, and L. E. Webb, J. Amer. Chem. Soc, 86, 2342 (1964)] was derived from X-ray data given by a crystal that subsequently was shown to be ClFeTPP. Orientational disorder of the ClFeTPP molecules in the crystal was shown to be primarily responsible for X-ray data that weee inconsistent only in a few essential details with the erroneous chemical formulation.7
20. J. L. Hoard, C. H. L. Kcnnard, and G. S. Smith, Inorg. Chem., 2, 1316 (1963)
21. M. D. Lind, M. J. Hamor, T. A. Hamor, and J. L. Hoard, Inorg. Chem., 3, 34 (1964).
22. D. M. Collins, R. Countryman, and J. L. Hoard, J. Amer. Chem. Soc, 94, 2066 (1972).
23. H. B. Gray, Adcan. Chem. Ser., No. 100, 365 (1971), and references cited therein.
24. W. S. Caughey, private communication.
25. J. A. Elvidge and A. B. P. Lever, Proc. Chem. Soc., 195 (1959)
26. G. Englesma, A. Yamamoto, E. Markham, and M. Calvin, J. Phys. Chem., 66, 2517 (1962). The product was originally formulated as the monomeric Mn(IV) species, MnPcPyO.
27. J. L. Hoard, Science, 174, 1295 (1971).
28. Cf. (a) A. Pidcock, R. E. Richards, and L. M. Venanzi, J. Chem. Soc. A, 1707 (1966)
29. L. M. Venanzi, Chem. Brit., 4, 162 (1968), for a discussion of synergistic mechanisms.
30. L. J. Radonovich, W. S. Caughey, and J. L. Hoard.