New ring-opening polymerization via a π-allylpalladium complex: 4. Palladium-catalyzed decarboxylative polymerization of cyclic carbonate

Polymer Bulletin

Volumn 36, Issue 3, 1996, Pages 265-272

  Suzuki, Masato ^a,b   Haruyama, Tetsuya ^a   Ii, Atsuhiko ^a   Saegusa, Takeo ^a,c  

^a KYOTO UNIVERSITY   (Japan)

^b TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^c Kyoto Research Park ^*  (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0013623381     PISSN: 01700839     EISSN: None     Source Type: Journal    
DOI: 10.1007/BF00319224     Document Type: Article

References (11)

1. Heck RF (1985) Palladium Reagents in Organic Syntheses, Academic Press, London
2. Suzuki M (1993) J Synth Org Chem, Jpn 51: 141
3. Tsuji J (1986) Tetrahedron 42: 4361
4. (a) Suzuki M, Sawada S, Saegusa T (1989) Macromolecules 22: 1505.
5. (b) Suzuki M, Sawada S, Yoshida S, Eberhardt A, Saegusa T (1993) Macromolecules 26: 4748
6. Suzuki M, Ii A, Saegusa T (1992) Macromolecules 25: 7071
7. Two methyl groups of I are introduced to avoid a side reaction, i.e., β-hydrogen elimination in π-allylpalladium intermediate. It is known that this type of reaction takes place to isomerize the related cyclic carbonate: Fujinami T, Suzuki T, Kamiya M, Fukuzawa S, Saka S (1985) Chem Lett: 199.
8. Takata T, Igarashi M, Endo T (1991) J Polym Sci, Polym Chem 29: 781, and references cited therein.
9. Ukai T, Kawazura H, Ishii Y (1974) J Organomet Chem 65: 253
10. It is known that cyclic carbonate related to I decarboxylatively reacts with carbon monooxide via the π-allylpalladium intermediate: Tamaru Y, Bando T, Hojo M, Yoshida Z (1987) Tetrahedron Lett 28: 3497.
11. Ishimori M, Tsuruta T (1963) Makromol Chem 64: 190