Radical substitution in the nickeladithiolene ring in bis(1-phenyl-1,2-ethenedithiolato)nickel(0)

Organometallics

Volumn 15, Issue 26, 1996, Pages 5664-5668

  Sugimori, Akira ^a   Tachiya, Naohisa ^a   Kajitani, Masatsugu ^a   Akiyama, Takeo ^a  

^a SOPHIA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0013572897     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om960698i     Document Type: Article

References (16)

1. Reviews: (a) Schrauzer, G. N. Acc. Chem. Res. 1969, 2, 72-80. (b) McCleverty, J. A. Prog. Inorg. Chem. 1969, 10, 49-221. (c) Burns, R. P.; McAuliffe, C. A. Adv. Inorg. Chem. Radiochem. 1979, 22, 303-348. (d) Mueller-Westerhoff, U. T.; Vance, B. In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon Press: Oxford, U.K., 1987; Vol. 2, pp 595-631. (e) Sugimori, A. Yuki Gosei Kagaku Kyokai Shi 1990, 48, 788-796.
2. Reviews: (a) Schrauzer, G. N. Acc. Chem. Res. 1969, 2, 72-80. (b) McCleverty, J. A. Prog. Inorg. Chem. 1969, 10, 49-221. (c) Burns, R. P.; McAuliffe, C. A. Adv. Inorg. Chem. Radiochem. 1979, 22, 303-348. (d) Mueller-Westerhoff, U. T.; Vance, B. In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon Press: Oxford, U.K., 1987; Vol. 2, pp 595-631. (e) Sugimori, A. Yuki Gosei Kagaku Kyokai Shi 1990, 48, 788-796.
3. Reviews: (a) Schrauzer, G. N. Acc. Chem. Res. 1969, 2, 72-80. (b) McCleverty, J. A. Prog. Inorg. Chem. 1969, 10, 49-221. (c) Burns, R. P.; McAuliffe, C. A. Adv. Inorg. Chem. Radiochem. 1979, 22, 303-348. (d) Mueller-Westerhoff, U. T.; Vance, B. In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon Press: Oxford, U.K., 1987; Vol. 2, pp 595-631. (e) Sugimori, A. Yuki Gosei Kagaku Kyokai Shi 1990, 48, 788-796.
4. Reviews: (a) Schrauzer, G. N. Acc. Chem. Res. 1969, 2, 72-80. (b) McCleverty, J. A. Prog. Inorg. Chem. 1969, 10, 49-221. (c) Burns, R. P.; McAuliffe, C. A. Adv. Inorg. Chem. Radiochem. 1979, 22, 303-348. (d) Mueller-Westerhoff, U. T.; Vance, B. In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon Press: Oxford, U.K., 1987; Vol. 2, pp 595-631. (e) Sugimori, A. Yuki Gosei Kagaku Kyokai Shi 1990, 48, 788-796.
5. Reviews: (a) Schrauzer, G. N. Acc. Chem. Res. 1969, 2, 72-80. (b) McCleverty, J. A. Prog. Inorg. Chem. 1969, 10, 49-221. (c) Burns, R. P.; McAuliffe, C. A. Adv. Inorg. Chem. Radiochem. 1979, 22, 303-348. (d) Mueller-Westerhoff, U. T.; Vance, B. In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon Press: Oxford, U.K., 1987; Vol. 2, pp 595-631. (e) Sugimori, A. Yuki Gosei Kagaku Kyokai Shi 1990, 48, 788-796.
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11. Sartain, D.; Truter, M. R. J. Chem. Soc. A 1967, 1264-1272.
12. The splitting of the signal of H in the nickeladithiolene ring at low temperature was not observed in the case of a trisubstituted nickeladithiolene, (1-phenyl-1,2-ethenedithiolato)(1,2-diphenyl-1,2-ethenedithiolato)nickel(O), for which no geometrical isomers are expected. Although the X-ray structure suggests an intermolecular interaction between Ni and S in the crystals, the NMR data for trisubstituted nickeladithiolene indicate that the complex exists in a single form. This excludes the monomer-dimer equilibrium in solution. The separation of the two signals in 1 is 9.8 Hz. This can not be explained by the coupling of protons.
13. The configurations of the substituents in the nickeladithiolene rings have not been determined. The adduct would be a mixture of the isomers.
14. Davison, A.; McCleverty, J. A.; Shawl, E. T.; Wharton, E. J. J. Am. Chem. Soc. 1967, 89, 830-832.
15. Bhattacharya, A. K.; Hortmann, A. G. J. Org. Chem. 1974, 39, 95-97.
16. Falares, P.; Mitsopoulou, C.-A.; Argyropoulos, D.; Lyris, E.; Psaroudakis, N.; Vrachnou, E.; Katakis, D. Inorg. Chem. 1995, 34, 4536-4542.