Mechanism of displacement of alkanes from photogenerated (alkane) Cr(CO)5 complexes

Journal of Coordination Chemistry

Volumn 47, Issue 3, 1999, Pages 409-416

  Dobson, Gerard R ^a   Zhang, Shulin ^a,b  

^a UNIVERSITY OF NORTH TEXAS   (United States)

^b PROCTER AND GAMBLE COMPANY   (United States)

Author keywords

Chromium; Flash photolysis; Kinetics; Metal carbonyl; N heptane

Indexed keywords

EID: 0013361969     PISSN: 00958972     EISSN: None     Source Type: Journal    
DOI: 10.1080/00958979908022225     Document Type: Article

References (17)

1. T. Lian, S.E. Bromberg, M.C. Asplund, H. Yang and C.B. Harris, J. Phys. Chem. 100, 11994 (1996), and references cited therein.
2. 5 intermediates generated after flash photolysis: (a) J.M. Kelly, D.V. Bent, H. Hermann, D. Schulte-Frohlinde and E.A. Koerner von Gustorf, J. Organomet. Chem. 69, 259 (1974); (b) J.M. Kelly, C. Long and R. Bonneau, J. Phys. Chem. 87, 3344 (1983); (c) G.R. Dobson, S. Zhang, V. Zang, H.C. Bajaj and R. van Eldik, Inorg. Chem. 29, 3477 (1990); (d) S. Zhang and G.R. Dobson, Polyhedron 9, 2511 (1990); (e) S. Zhang and G.R. Dobson, Inorg. Chim. Acta 11, 2447 (1992); (f) S. Ladogana, S.K. Nayak, J.P. Smit and G.R. Dobson, Organometallics 16, 3051 (1997); (g) S. Ladogana, S.K. Nayak, J.P. Smit and G.R. Dobson, Inorg. Chim. Acta 267, 49 (1998); (h) S. Ladogana, G.R. Dobson and J.P. Smit, Inorg. Chim. Acta 278, 202 (1998).
3. 5 intermediates generated after flash photolysis: (a) J.M. Kelly, D.V. Bent, H. Hermann, D. Schulte-Frohlinde and E.A. Koerner von Gustorf, J. Organomet. Chem. 69, 259 (1974); (b) J.M. Kelly, C. Long and R. Bonneau, J. Phys. Chem. 87, 3344 (1983); (c) G.R. Dobson, S. Zhang, V. Zang, H.C. Bajaj and R. van Eldik, Inorg. Chem. 29, 3477 (1990); (d) S. Zhang and G.R. Dobson, Polyhedron 9, 2511 (1990); (e) S. Zhang and G.R. Dobson, Inorg. Chim. Acta 11, 2447 (1992); (f) S. Ladogana, S.K. Nayak, J.P. Smit and G.R. Dobson, Organometallics 16, 3051 (1997); (g) S. Ladogana, S.K. Nayak, J.P. Smit and G.R. Dobson, Inorg. Chim. Acta 267, 49 (1998); (h) S. Ladogana, G.R. Dobson and J.P. Smit, Inorg. Chim. Acta 278, 202 (1998).
4. 5 intermediates generated after flash photolysis: (a) J.M. Kelly, D.V. Bent, H. Hermann, D. Schulte-Frohlinde and E.A. Koerner von Gustorf, J. Organomet. Chem. 69, 259 (1974); (b) J.M. Kelly, C. Long and R. Bonneau, J. Phys. Chem. 87, 3344 (1983); (c) G.R. Dobson, S. Zhang, V. Zang, H.C. Bajaj and R. van Eldik, Inorg. Chem. 29, 3477 (1990); (d) S. Zhang and G.R. Dobson, Polyhedron 9, 2511 (1990); (e) S. Zhang and G.R. Dobson, Inorg. Chim. Acta 11, 2447 (1992); (f) S. Ladogana, S.K. Nayak, J.P. Smit and G.R. Dobson, Organometallics 16, 3051 (1997); (g) S. Ladogana, S.K. Nayak, J.P. Smit and G.R. Dobson, Inorg. Chim. Acta 267, 49 (1998); (h) S. Ladogana, G.R. Dobson and J.P. Smit, Inorg. Chim. Acta 278, 202 (1998).
5. 5 intermediates generated after flash photolysis: (a) J.M. Kelly, D.V. Bent, H. Hermann, D. Schulte-Frohlinde and E.A. Koerner von Gustorf, J. Organomet. Chem. 69, 259 (1974); (b) J.M. Kelly, C. Long and R. Bonneau, J. Phys. Chem. 87, 3344 (1983); (c) G.R. Dobson, S. Zhang, V. Zang, H.C. Bajaj and R. van Eldik, Inorg. Chem. 29, 3477 (1990); (d) S. Zhang and G.R. Dobson, Polyhedron 9, 2511 (1990); (e) S. Zhang and G.R. Dobson, Inorg. Chim. Acta 11, 2447 (1992); (f) S. Ladogana, S.K. Nayak, J.P. Smit and G.R. Dobson, Organometallics 16, 3051 (1997); (g) S. Ladogana, S.K. Nayak, J.P. Smit and G.R. Dobson, Inorg. Chim. Acta 267, 49 (1998); (h) S. Ladogana, G.R. Dobson and J.P. Smit, Inorg. Chim. Acta 278, 202 (1998).
6. 5 intermediates generated after flash photolysis: (a) J.M. Kelly, D.V. Bent, H. Hermann, D. Schulte-Frohlinde and E.A. Koerner von Gustorf, J. Organomet. Chem. 69, 259 (1974); (b) J.M. Kelly, C. Long and R. Bonneau, J. Phys. Chem. 87, 3344 (1983); (c) G.R. Dobson, S. Zhang, V. Zang, H.C. Bajaj and R. van Eldik, Inorg. Chem. 29, 3477 (1990); (d) S. Zhang and G.R. Dobson, Polyhedron 9, 2511 (1990); (e) S. Zhang and G.R. Dobson, Inorg. Chim. Acta 11, 2447 (1992); (f) S. Ladogana, S.K. Nayak, J.P. Smit and G.R. Dobson, Organometallics 16, 3051 (1997); (g) S. Ladogana, S.K. Nayak, J.P. Smit and G.R. Dobson, Inorg. Chim. Acta 267, 49 (1998); (h) S. Ladogana, G.R. Dobson and J.P. Smit, Inorg. Chim. Acta 278, 202 (1998).
7. 5 intermediates generated after flash photolysis: (a) J.M. Kelly, D.V. Bent, H. Hermann, D. Schulte-Frohlinde and E.A. Koerner von Gustorf, J. Organomet. Chem. 69, 259 (1974); (b) J.M. Kelly, C. Long and R. Bonneau, J. Phys. Chem. 87, 3344 (1983); (c) G.R. Dobson, S. Zhang, V. Zang, H.C. Bajaj and R. van Eldik, Inorg. Chem. 29, 3477 (1990); (d) S. Zhang and G.R. Dobson, Polyhedron 9, 2511 (1990); (e) S. Zhang and G.R. Dobson, Inorg. Chim. Acta 11, 2447 (1992); (f) S. Ladogana, S.K. Nayak, J.P. Smit and G.R. Dobson, Organometallics 16, 3051 (1997); (g) S. Ladogana, S.K. Nayak, J.P. Smit and G.R. Dobson, Inorg. Chim. Acta 267, 49 (1998); (h) S. Ladogana, G.R. Dobson and J.P. Smit, Inorg. Chim. Acta 278, 202 (1998).
8. 5 intermediates generated after flash photolysis: (a) J.M. Kelly, D.V. Bent, H. Hermann, D. Schulte-Frohlinde and E.A. Koerner von Gustorf, J. Organomet. Chem. 69, 259 (1974); (b) J.M. Kelly, C. Long and R. Bonneau, J. Phys. Chem. 87, 3344 (1983); (c) G.R. Dobson, S. Zhang, V. Zang, H.C. Bajaj and R. van Eldik, Inorg. Chem. 29, 3477 (1990); (d) S. Zhang and G.R. Dobson, Polyhedron 9, 2511 (1990); (e) S. Zhang and G.R. Dobson, Inorg. Chim. Acta 11, 2447 (1992); (f) S. Ladogana, S.K. Nayak, J.P. Smit and G.R. Dobson, Organometallics 16, 3051 (1997); (g) S. Ladogana, S.K. Nayak, J.P. Smit and G.R. Dobson, Inorg. Chim. Acta 267, 49 (1998); (h) S. Ladogana, G.R. Dobson and J.P. Smit, Inorg. Chim. Acta 278, 202 (1998).
9. 5 intermediates generated after flash photolysis: (a) J.M. Kelly, D.V. Bent, H. Hermann, D. Schulte-Frohlinde and E.A. Koerner von Gustorf, J. Organomet. Chem. 69, 259 (1974); (b) J.M. Kelly, C. Long and R. Bonneau, J. Phys. Chem. 87, 3344 (1983); (c) G.R. Dobson, S. Zhang, V. Zang, H.C. Bajaj and R. van Eldik, Inorg. Chem. 29, 3477 (1990); (d) S. Zhang and G.R. Dobson, Polyhedron 9, 2511 (1990); (e) S. Zhang and G.R. Dobson, Inorg. Chim. Acta 11, 2447 (1992); (f) S. Ladogana, S.K. Nayak, J.P. Smit and G.R. Dobson, Organometallics 16, 3051 (1997); (g) S. Ladogana, S.K. Nayak, J.P. Smit and G.R. Dobson, Inorg. Chim. Acta 267, 49 (1998); (h) S. Ladogana, G.R. Dobson and J.P. Smit, Inorg. Chim. Acta 278, 202 (1998).
10. S. Ladogana, S.K. Nayak, J.P. Smit and G.R. Dobson, Inorg. Chem. 36, 650 (1997).
11. w have several binding modes to Cr available to them: "agostic," through a -C-H-Cr two-electron, three-center interaction, via either an arene ring-center or edge, or through a lone pair on a substituted halogen, Cl or Br; see Refs. [2,3].
12. (a) M. Brookhart and M.L.H. Green, J. Organomet. Chem. 250, 395 (1983);
13. (b) J.Y. Saillard and R. Hoffmann, J. Am. Chem. Soc. 106, 2006 (1984);
14. (c) M. Brookhart, M.L.H. Green, and L.-L. Wong, Prog. Inorg. Chem. 36, 2 (1988).
15. G.K. Yang, V. Vaida and K.S. Peters, Polyhedron 7, 1619 (1988).
16. G.R. Dobson, S. Ladogana and S.K. Nayak, Inorg. Chem. (manuscript submitted).
17. T.L. Burkey, in, Energetics of Organometallic Species (Kluwer Academic Publishers, Dordrecht, The Netherlands, 1992), p. 76.