Synthesis of bis(trimethylstannyl)aryl compounds via an SRN1 mechanism with intermediacy of monosubstitution products

Organometallics

Volumn 21, Issue 26, 2002, Pages 5874-5878

  Chopa, Alicia B ^a   Lockhart, María T ^a   Silbestri, Gustavo F ^a  

^a UNIVERSIDAD NACIONAL DEL SUR   (Argentina)

Author keywords

[No Author keywords available]

Indexed keywords

MONOSUBSTITUTION PRODUCTS;

ESTERS; IRRADIATION; NEGATIVE IONS; PHENOLS; SYNTHESIS (CHEMICAL);

ORGANOMETALLICS;

EID: 0013069929     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om020622o     Document Type: Article

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10. 1
11. RN1Mechanism; ACS Monograph 178; American Chemical Society: Washington, DC, 1983.
12. Unpublished results.
13. These results are in agreement with those obtained by Bunnett in the reaction between m-chloroiodobenzene and diethyl phosphite ion: Bunnett, J. F.; Shafer, S. J. J. Org. Chem. 1978, 43, 1877.
14. To be used as the starting material in selective substitution reactions (work in progress).
15. 21
16. 8
17. 2
18. 3), 373 (13), 252 (100).
19. +), 378 (9, M - 28), 349 (11), 252 (79).
20. Vogel's Textbook of Practical Organic Chemistry, 4th ed.; Longman: New York, 1978; p 613.
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22. H,P = 5.8-6.2 Hz) as well as the absorption due to the aryl groups.