Stereoelectronic Effects in the Reactions of Epimeric 2-Aryloxy-2-oxy-1,3,2-dioxaphosphorinanes and Oxazaphosphorinanes

Journal of the American Chemical Society

Volumn 102, Issue 15, 1980, Pages 5077-5081

  Gorenstein, David G ^a   Rowell, Robert ^a   Findlay, John ^a  

^a UNIVERSITY OF ILLINOIS AT CHICAGO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0012820897     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00535a044     Document Type: Article

References (49)

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49. This picture is supported by the near-equal rates of hydrolysis (* O. 2 kcal/mol) and ground-state energies (° O. 1 kcal/mol) for the epimeric tetracyclic phosphordiamidates 11. Again (R. Rowell, unpublished) the b isomer is in a boat-type conformation