Oxidation of ruthenium hydrides (η5-C5H4R)Ru(PPh3)2H (R=H, tBu, CH2Ph, CTol3). X-ray crystal structure determination of (η5-C5H4(CTol3))Ru(PPh 3)2H and an electrochemical study of its stable cation radical

Inorganica Chimica Acta

Volumn 259, Issue 1-2, 1997, Pages 281-290

  Rømming, Christian ^a   Smith, Kjell Tore ^a   Tilset, Mats ^a  

^a UNIVERSITY OF OSLO   (Norway)

Author keywords

Crystal structures; Cyclopentadienyl complexes; Electrochemistry; Hydride complexes; Ruthenium complexes

Indexed keywords

CRYSTAL STRUCTURE; CYCLIC VOLTAMMETRY; ELECTROCHEMISTRY; ELECTRON SPIN RESONANCE SPECTROSCOPY; HYDRIDES; MOLECULES; ORGANIC POLYMERS; OXIDATION; POSITIVE IONS; X RAYS;

CYCLIC VOLTAMMOGRAMS; CYCLOPENTADIENYL COMPLEXES; ELECTROCHEMICAL STUDIES; HYDRIDE COMPLEXES; HYPERFINE STRUCTURE; REVERSIBLE OXIDATION; RUTHENIUM COMPLEXES; X RAY CRYSTAL STRUCTURES;

RUTHENIUM COMPOUNDS;

EID: 0012803018     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0020-1693(97)05467-4     Document Type: Article

References (51)

1. (a) V. Skagestad and M. Tilset, J. Am. Chem. Soc., 115 (1993) 5077;
2. (b) O.B. Ryan, M. Tilset and V.D. Parker, J. Am. Chem. Soc., 112 (1990) 2618;
3. (c) O.B. Ryan, M. Tilset and V.D. Parker, Organometallics, 10 (1991) 298;
4. (d) M. Tilset, J. Am. Chem. Soc., 114 (1992) 2740.
5. (a) R.J. Klingler, J.C. Huffman and J.K. Kochi, J. Am. Chem. Soc., 102 (1980) 208;
6. (b) M.R. Detty and W.D. Jones, J. Am. Chem. Soc., 109 (1987) 5666;
7. (c) L. Chen and J.A. Davies, Inorg. Chim. Acta, 175 (1990) 41;
8. (d) D.E. Westerberg, L.F. Rhodes, J. Edwin, W.E. Geiger and K.G. Caulton, Inorg. Chem., 30 (1991) 1107;
9. (e) O.B. Ryan and M. Tilset, J. Am. Chem. Soc., 113 (1991) 9554;
10. (f) O.B. Ryan, K.-T. Smith and M. Tilset, J. Organomet. Chem., 421 (1991) 315;
11. (g) C. Amatore, J.J.R. Fraústo Da Silva, M.F.C. Guedes Da Silva, A.J.L. Pombeiro and J.-N. Verpeaux, J. Chem. Soc., Chem. Commun., (1992) 1289;
12. (h) M.A.N.D.A. Lemos and A.J.L. Pombeiro, J. Organomet. Chem., 438 (1992) 159;
13. (i) A. Zlota, M. Tilset and K.G. Caulton, Inorg. Chem., 32 (1993) 3816.
14. K.-T. Smith, M. Tilset, S.S. Kristjánsdóttir and J.R. Norton, Inorg. Chem., 34 (1995) 6497.
15. K.-T. Smith, C. Rømming and M. Tilset, J. Am. Chem. Soc., 115 (1993) 8681.
16. O.B. Ryan, K.-T. Smith and M. Tilset, J. Organomet. Chem., 421 (1991) 315.
17. N.S. Moe, Anal. Chem., 46 (1994) 968.
18. T. Wilczewski, M. Bochenska and J.F. Biernat, J. Organomet. Chem., 215 (1981) 87.
19. T. Leigh, Monatsh. Chem., (1964) 3294.
20. U.M. Dzhemilev, A.G. Ibragimov, E.V. Gribanora and L.M. Khalilov, Izv. Akad. Nauk., 11 (1985) 2562.
21. H.J. Dauben, L.R. Honnen and K.M. Harmon, J. Org. Chem., 25 (1960) 1442.
22. SMART and SAINT, area-detector control and integration software, Siemens Analytical X-ray Instrument Inc., Madison, WI, USA.
23. G.M. Sheldrick, personal communication, 1996.
24. G.M. Sheldrick, SHELXTL, Version 5, Siemens Analytical Instruments Inc., Madison, WI, USA.
25. F.R. Lemke and L. Brammer, Organometallics, 14 (1995) 3980.
26. S.A. Lister, A.D. Redhouse and S.J. Simpson, Acta Crystallogr., Sect. C, 48 (1992) 1661.
27. M.I. Bruce, I.R. Butler, W.R. Cullen, G.A. Koutsantonis, M.R. Snow and E.R.T. Tiekink, Aust. J. Chem., 41 (1988) 963.
28. R.T. Hembre, J.S. McQueen and V.W. Day, J. Am. Chem. Soc., 118 (1996) 798.
29. (a) F. Mao, S.K. Sur and D.R. Tyler, J. Am. Chem. Soc., 111 (1989) 7627;
30. (b) F. Mao, C.E. Philbin, T.J.R. Weakley and D.R. Tyler, Organometallics, 9 (1990) 1510;
31. (c) D. Mynott, H. Lehmkuhl, E.-M. Kremzer and E. Joussen, Angew. Chem., Int. Ed. Engl., 29 (1990) 289;
32. (d) H. Sitzmann, Chem. Ber., 123 (1990) 2311;
33. (e) M. Fei, S.K. Sur and D.R. Tyler, Organometallics, 10 (1991) 419.
34. (a) C. Roger, P. Hamon, L. Toupet, H. Rabaa, J.-Y. Saillard, J.-R. Hamon and C. Lapinte, Organometallics, 10 (1991) 1045;
35. (b) P. Hamon, L. Toupet, J.-R. Hamon and C. Lapinte, Organometallics, 11 (1992) 1429;
36. (c) P. Hamon, J.-R. Hamon and C. Lapinte, J. Chem. Soc., Chem. Commun., (1992) 1602;
37. (d) J. Morrow, D. Catheline, M.-H. Desbois, J.M. Manriquez, J. Ruiz and D. Astruc, Organometallics, 6 (1987) 2605;
38. (e) J.R. Morrow and D. Astruc, Bull. Soc. Chim. Fr., 129 (1992) 319.
39. N.G. Connelly and I. Manners, J. Chem. Soc., Dalton Trans., (1989) 283.
40. U. Koelle, H. Lueken, K. Handrick, H. Schilder, J.K. Burdett and S. Balleza, Inorg. Chem., 34 (1995) 6273.
41. D.H. Evans, Chem. Rev., 90 (1990) 739.
42. A.M. Bond, R. Colton, S.W. Feldberg, P.J. Mahon and T. Whyte, Organometallics, 10 (1991) 3320.
43. (a) M. Rudolph, D.P. Reddy and S.W. Feldberg, Anal. Chem., 66 (1994) 589A;
44. (b) Trademark of Bioanalytical Systems Inc., West Lafayette, IN.
45. (a) D. Astruc, Electron Transfer and Radical Processes in Transition-Metal Chemistry, Verlag Chemie, Weinheim, 1995;
46. (b) Chem. Rev., 88 (1988) 1189;
47. (c) M.C. Baird, Chem. Rev., 88 (1988) 1217;
48. (d) D.R. Tyler, Prog. Inorg. Chem., 36 (1988) 125;
49. (e) W.C. Trogler (ed.), Organometallic Radical Processes, Elsevier, Amsterdam, 1990.
50. (a) P. Diversi, S. Iacoponi, G. Ingrosso, F. Laschi, A. Lucherini and P. Zanello, J. Chem. Soc., Dalton Trans., (1993) 351;
51. (b) P. Diversi, S. Iacoponi, G. Ingrosso, F. Laschi, A. Lucherini, C. Pinzino, G. Uccello-Barrettaand P. Zanello, Organometallics, 14 (1995) 3275.