메뉴 건너뛰기




Volumn 344, Issue 6-7, 2002, Pages 631-633

A mechanism switch in enyne metathesis reactions involving rearrangement: Influence of heteroatoms in the propargylic position

Author keywords

Alkenes; Cycloaddition; Enyne metathesis; Metathesis; Rearrangement; Ruthenium

Indexed keywords


EID: 0012748919     PISSN: 16154150     EISSN: 15213897     Source Type: Journal    
DOI: 10.1002/1615-4169(200208)344:6/7<631::AID-ADSC631>3.0.CO;2-W     Document Type: Article
Times cited : (62)

References (23)
  • 19
    • 0035929110 scopus 로고    scopus 로고
    • These reactions have been reported only with highly electron-deficient olefins, which are generally incompatible with catalyst 1: S. Randl, S. J. Connon, S. Blechert, Chem. Commun. 2001, 1796-1797.
    • (2001) Chem. Commun. , pp. 1796-1797
    • Randl, S.1    Connon, S.J.2    Blechert, S.3
  • 20
    • 33751275404 scopus 로고    scopus 로고
    • note
    • Interestingly, using the more active 2 and methyl vinyl ketone, both selective CM at the side-chain terminal olefin and bis-CM functionalisation were possible in good yields (> 65%) using either 1.2 or 4 equivalents of the CM partner, respectively; to our knowledge the latter is the first example of a butadiene moiety participating in a catalytic CM reaction.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.