Unexpected formation of the isopropylamine complex [2,3,4,5-Ph4(η4-C4CO)](CO)2Ru(H 2NCHME2) in the attempted synthesis of an isopropyl alcohol complex

Organometallics

Volumn 21, Issue 9, 2002, Pages 1955-1959

  Casey, Charles P ^a   Bikzhanova, Galina A ^a   Bäckvall, Jan E ^b   Johansson, Lars ^b   Park, Jaiwook ^c   Kim, Yu Hwan ^c  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

^b STOCKHOLM UNIVERSITY   (Sweden)

^c Pohang University of Science and Technology (POSTECH)   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONE; ALCOHOLS; AMMONIUM COMPOUNDS; MASS SPECTROMETERS; RUTHENIUM COMPOUNDS; SYNTHESIS (CHEMICAL); X RAY SPECTROMETERS;

ELEMENTAL ANALYSIS;

ORGANOMETALLICS;

EID: 0012462507     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om020097t     Document Type: Article

References (21)

1. (a) Shvo, Y.; Czarkie, D.; Rahamim, Y. J. Am. Chem. Soc. 1086, 108, 7400.
2. (b) Menashe, N.; Shvo, Y. Organometallics 1991, 10, 3885.
3. (c) Menashe, N.; Salant, E.; Shvo, Y. J. Organomet. Chem. 1996, 514, 97.
4. (a) Almeida, M. L. S.; Beller, M.; Wang, G.-Z.; Bäckvall, J. E. Chem. Eur. J. 1996, 2, 1533.
5. (b) Larsson, A. L. E.; Persson, B. A.; B̈ckvall, J. E. Angew. Chem., Int. Ed. Engl. 1997, 36, 1211.
6. (c) Persson, B. A.; Larsson. A. L. E.; Le Ray, M.; Bäckvall, J. E. J. Am. Chem. Soc. 1999, 121, 1645.
7. (d) Persson, B. A.; Huerta, F. F.; Bäckvall, J. E. J. Org. Chem. 1999, 64, 5237.
8. (e) Huerta, F. F.; Laxmi, Y. R. S.; Bäckvall, J. E. Org. Lett. 2000, 2, 1037.
9. (f) Laxmi, Y. R. S.; Bäckvall, J. E. Chem. Commun. 2000, 611.
10. Abed, M.; Goldberg, I.; Stein, Z.; Shvo, Y. Organometallics 1988, 7, 2054.
11. Csjernyik, G.; Éll, A. H.; Fadini, L.; Pugin, B.; Bäckvall, J. E. J. Org. Chem. 2002, 67, 1657.
12. Shvo proposed that the hydrogenation of alkenes and alkynes proceeds through, a ring-slip mechanism: Shvo, Y.; Goldberg, I.; Czerkie, D.; Reshef, D.; Stein, Z. Organometallics 1607, 16, 133.
13. Casey, C. P.; Singer, S. W.; Powell, D. R.; Hayashi, R. K.; Kavana, M. J. Am. Chem. Soc. 2001, 123, 1090.
14. Jung, H. M.; Shin, S. T.; Kim, Y. H.; Kim, M.-J.; Park, J. Organometallica 2001, 20, 3870.
15. 11H NMR spectra of A also showed integration for 2H for the two peaks at δ 2.44 and approximately 1:3.5:7:8.75:7:3.5:1 intensity for the seven inner lines of the δ 2.87 resonance. These discrepancies were initially attributed to the presence of water as an impurity.
16. Shvo, Y.; Abed, M.; Blum, Y.; Laine, R. M. Isr. J. Chem. 1986, 27, 267.
17. 6
18. The revised crystallographic data have been deposited with the Cambridge Crystallographic Data Centre (CCDC 176947).
19. - of 4a: mlz (calcd, obsd) 605 (19, 22), 604 (54, 59), 603 (34, 47), 602 (100, 100), 601 (58, 62), 600 (45, 68).
20. - of 4a: mlz (calcd, obsd) 605 (19, 22), 604 (54, 59), 603 (34, 47), 602 (100, 100), 601 (58, 62), 600 (45, 68).
21. 3Ru: C, 67.99; H, 4.87; N, 2.33. Found: C, 67.97; H, 4.74; N, 2.40.