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Rowe D.M. Chemical Rubber Boca Raton, Florida, This article explains in detail some phenomenological rules for selecting good thermoelectric materials. A description of the electron-glass/phonon crystal idea, and a large list of possible new thermoelectric materials is given. Other chapters in this handbook may also be of interest.
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Slack GA. New materials and performance limits for thermoelectrics. Rowe DM. CRC Handbook of Thermoelectrics. 1995;407-440 Chemical Rubber, Boca Raton, Florida, This article explains in detail some phenomenological rules for selecting good thermoelectric materials. A description of the electron-glass/phonon crystal idea, and a large list of possible new thermoelectric materials is given. Other chapters in this handbook may also be of interest.
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CRC Handbook of Thermoelectrics
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Slack, G.A.1
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0001922710
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H. Ehrenreich, Spaepen F. Academic Press, Inc This is an excellent and detailed review of the field of thermoelectrics from its early origins to present day research efforts. Both theory and materials are covered
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Mahan GD. Good thermoelectrics. Ehrenreich H, Spaepen F. Solid State Physics. 1997;Academic Press, Inc, This is an excellent and detailed review of the field of thermoelectrics from its early origins to present day research efforts. Both theory and materials are covered.
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Cahill DG, Watson SK, Pohl RO. Lower limit to the thermal conductivity of disordered crystals. Phys Rev B. 46:1992;6131-6140.
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3-type structure and isotopic lanthanoid-transition metal polyphosphides. Acta Crystallogr B. 33:1977;3401-3405.
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Meisner GP. Superconductivity and magnetic order in ternary rare earth transition metal phoshides. Physica B. 108:1981;763-765.
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The thermal and electrical transport results given in this paper provided the first published evidence that this class of materials may be of interest for thermoelectric applications.
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12. J Appl Phys. 77:1995;3777-3781 The thermal and electrical transport results given in this paper provided the first published evidence that this class of materials may be of interest for thermoelectric applications.
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J Appl Phys
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Morelli, D.T.1
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A single crystal with a very low carrier concentration was investigated. Transport measurements indicated the presence of two energy gaps, consistent with band structure calculations. Ionized impurity scattering dominated in this crystal.
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3. Phys Rev B. 52:1995;4926-4929 A single crystal with a very low carrier concentration was investigated. Transport measurements indicated the presence of two energy gaps, consistent with band structure calculations. Ionized impurity scattering dominated in this crystal.
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Mandrus, D.1
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Filled skutterudite antimonides: A new class of thermoelectric materials
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High values for ZT were found in this class of materials at elevated temperatures. These data showed that 'rattling' atoms could be used to lower the thermal conductivity of the crystal without destroying the electronic transport.
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Sales BC, Mandrus D, Williams RK. Filled skutterudite antimonides: a new class of thermoelectric materials. Science. 272:1996;1325-1328 High values for ZT were found in this class of materials at elevated temperatures. These data showed that 'rattling' atoms could be used to lower the thermal conductivity of the crystal without destroying the electronic transport.
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Science
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0001056797
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The effect of rare-earth filling on the lattice thermal conductivity of skutterudites
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A very careful study that found that the smaller the size of the rare earth ion 'rattler', the smaller the thermal conductivity of the lattice. Low thermal conductivity values (10-20 mW/cm-K) were found for all of the filled skutterudites.
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Nolas GS, Slack GA, Morelli DT, Tritt TM, Ehrlich AC. The effect of rare-earth filling on the lattice thermal conductivity of skutterudites. J Appl Phys. 79:1996;4002-4008 A very careful study that found that the smaller the size of the rare earth ion 'rattler', the smaller the thermal conductivity of the lattice. Low thermal conductivity values (10-20 mW/cm-K) were found for all of the filled skutterudites.
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Nolas, G.S.1
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The authors speculate that the unusually low thermal conductivity observed for this alloy is related to strong phonon scattering from Ru ions with a mixed valence.
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3. J Appl Phys. 79:1996;8419-8426 The authors speculate that the unusually low thermal conductivity observed for this alloy is related to strong phonon scattering from Ru ions with a mixed valence.
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J Appl Phys
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Caillat, T.1
Kulleck, J.2
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Singh DJ, Pickett WE. Skutterudite antimonides: quasilinear bands and unusual transport. Phys Rev B. 50:1994;11235-11238.
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Singh, D.J.1
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0000575433
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3
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These calculations provide a useful starting point for comparing the lattice dynamics from a filled and unfilled skutterudite. A difference in the phonon density of states of the two materials can be related to the large difference in thermal conductivity.
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3. Phys Rev B. 53:1996;6273-6282 These calculations provide a useful starting point for comparing the lattice dynamics from a filled and unfilled skutterudite. A difference in the phonon density of states of the two materials can be related to the large difference in thermal conductivity.
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Phys Rev B
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Feldman, J.L.1
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Caillat T. Piscataway, New Jersey: IEEE Catalog 96TH8169
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Fleurial JP, Borshchevsky A, Caillat T, Morelli DT, Meisner GP. High figure of merit in Ce-filled skutterudites. Caillat T. Proceedings of the XV International Conference on Thermoelectrics: 1996 Mar 26-29; Pasadena CA. 1996;91-95 IEEE Catalog 96TH8169, Piscataway, New Jersey.
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Fleurial, J.P.1
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What electronic structure provides the largest figure of merit? Using a general formula to describe the transport coefficients, the authors found that a delta-shaped transport distribution maximized ZT. The transport distribution included the density of states and the energy dependent scattering rate.
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Mahan GD, Sofo JO. The best thermoelectric. Proc Natl Acad Sci USA. 93:1996;7436-7439 What electronic structure provides the largest figure of merit? Using a general formula to describe the transport coefficients, the authors found that a delta-shaped transport distribution maximized ZT. The transport distribution included the density of states and the energy dependent scattering rate.
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Proc Natl Acad Sci USA
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This is a good introduction to the concept of a hybridization gap and illustrates the failure of single-electron band structure calculations.
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Mandrus D, Sarrao JL, Migliori A, Thompson JD, Fisk Z. Thermodynamics of FeSi. Phys Rev B. 51:1995;4763-4767 This is a good introduction to the concept of a hybridization gap and illustrates the failure of single-electron band structure calculations.
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Phys Rev B
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Mandrus, D.1
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Bhattacharjee AK, Coqblin B. Thermal conductivity of cerium compounds. Phys Rev B. 38:1988;338-344.
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G. Oomi, H. Fujii, Fujita T. New York: Plenum Press
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Bauer E. Thermal conductivity of Ce and Yb based Kondo compounds. Oomi G, Fujii H, Fujita T. Transport and Thermal Properties of f-Electron Systems. 1993;133-143 Plenum Press, New York.
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Hicks LD, Dresselhaus MS. Effect of quantum-well structures on the thermoelectric figure of merit. Phys Rev B. 47:1993;12727-12731.
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Hicks LD, Harman TC, Dresselhaus MS. Use of quantum-well superlattices to obtain a high figure of merit from nonconventional thermoelectric materials. Appl Phys Lett. 63:1993;3230-3232.
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0000695378
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Experimental study of the effect of quantum-well structures on the thermoelectric figure of merit
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Beautiful experimental work that illustrates the enhancement of ZT within the quantum well. The data agrees well with 2D free electron calculations.
-
Hicks LD, Harman TC, Sun X, Dresselhaus MS. Experimental study of the effect of quantum-well structures on the thermoelectric figure of merit. Phys Rev B. 53:1996;10493-10496 Beautiful experimental work that illustrates the enhancement of ZT within the quantum well. The data agrees well with 2D free electron calculations.
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Phys Rev B
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Hicks, L.D.1
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0030180707
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Most of the experimental details for the work described in [36] are given in this paper along with additional experimental data.
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Harman TC, Spears DL, Manfra MJ. High thermoelectric figures of merit in PbTe quantum wells. J Electron Mater. 25:1996;1121-1127 Most of the experimental details for the work described in [36] are given in this paper along with additional experimental data.
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Caillat T. IEEE Catalog 96TH8169 An honest evaluation of some of the problems associated with trying to fabricate multilayer thermoelectric films using magnetron sputtering.
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Wagner AV, Foreman RJ, Summers LJ, Barbee TW, Farmer JC. Synthesis and evaluation of thermoelectric multilayer films. Caillat T. Proceedings of the XV International Conference on Thermoelectrics: 1996 March 26-29; Pasadena CA. 1996;459-463 IEEE Catalog 96TH8169, An honest evaluation of some of the problems associated with trying to fabricate multilayer thermoelectric films using magnetron sputtering.
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Proceedings of the XV International Conference on Thermoelectrics: 1996 March 26-29; Pasadena CA
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Wagner, A.V.1
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Sofo JO, Mahan GD. Thermoelectric figure of merit of superlattices. Appl Phys Lett. 65:1994;2690-2693.
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Model calculations indicate that ZT for the entire superlattice structure (including barrier layers) is at best only about 20% higher than ZT values obtained with bulk materials.
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Broido DA, Reinecke TL. Effect of superlattice structure on the thermoelectric figure of merit. Phys Rev B. 51:1995;13797-13800 Model calculations indicate that ZT for the entire superlattice structure (including barrier layers) is at best only about 20% higher than ZT values obtained with bulk materials.
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Lin-Chung PJ, Reinecke TL. Thermoelectric figure of merit of composite superlattice systems. Phys Rev B. 51:1995;13244-13248.
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0002109914
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Thermoelectric figure of merit of quantum wire superlattices
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Model calculations indicate that the ZT values for a quantum wire system can be significantly higher (2-3 times) than those attainable with bulk materials or in a superlattice structure.
-
Broida DA, Reinecke TL. Thermoelectric figure of merit of quantum wire superlattices. Appl Phys Lett. 67:1995;100-102 Model calculations indicate that the ZT values for a quantum wire system can be significantly higher (2-3 times) than those attainable with bulk materials or in a superlattice structure.
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