Chemistry of Thiophene, Pyridine, and Cyclohexylamine on Ni/MoSx and Ni/S/Mo(110) Surfaces: Role of Nickel in Hydrodesulfurization and Hydrodenitrogenation Processes

Journal of Physical Chemistry B

Volumn 103, Issue 39, 1999, Pages 8310-8318

  Rodriguez, José A ^a   Dvorak, Joseph ^a   Jirsak, Tomas ^a   Li, Si Y ^a   Hrbek, Jan ^a   Capitano, Adam T ^b   Gabelnick, Aaron M ^b   Gland, John L ^b  

^a BROOKHAVEN NATIONAL LABORATORY   (United States)

^b UNIVERSITY OF MICHIGAN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0012158506     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp991683b     Document Type: Article

References (64)

1. Speight, J. G. The Chemistry and Technology of Petroleum, 2nd ed; Dekker: New York, 1991.
2. (a) Satterfield, C. N. Heterogeneous Catalysis in Practice; McGraw-Hill: New York, 1980.
3. (b) Thomas, J. M.; Thomas, W. J. Principles and Practice of Heterogeneous Catalysis; VCH: New York, 1997.
4. (c) Topsøe, H.; Clausen, B. S.; Massoth, F. E. Hydrotreating Catalysis: Science and Engineering; Springer-Verlag: Berlin, 1996.
5. Delmon, B. Bull. Soc. Chim. Belg. 1995, 104, 173.
6. (a) Rodriguez, J. A.; Hrbek, J. Acc. Chem. Res., in press.
7. (b) Bartholomew, C. H.; Agrawal, P. K.; Katzer, J. R. Adv. Catal. 1982, 31, 135.
8. Stern, A. C.; Boubel, R. W.; Turner, D. B.; Fox, D. L. Fundamentals of Air Pollution, 2nd ed; Academic Press: Orlando, 1984.
9. Chianelli, R. R.; Daage, M.; Ledoux, M. J. Adv. Catal. 1994, 40, 177.
10. Pecoraro, T. A.; Chianelli, R. R. J. Catal. 1981, 67, 430.
11. Ho, T. C. Catal. Rev. Sci. Eng. 1988, 30, 117.
12. Harris, S.; Chianelli, R. R. J. Catal. 1986, 98, 17.
13. Brito, J. L.; Barbosa, A. L. J. Catal.1997, 171, 467.
14. Startsev, A. N. Catal. Rev. Sci. Eng. 1995, 37, 353.
15. Zonnevylle, M.; Hoffmann, R.; Harris, S. Surf. Sci. 1988, 199, 320.
16. Rodriguez, J. A. J. Phys. Chem. B 1997, 101, 7524.
17. (a) Topsøe, H.; Clausen, B. S.; Topsøe, N.-Y.; Hyldtoft, J.; Nørskov, J. K. Symposium on the Mechanism of HDS/HDN Reactions; Division of Petroleum Chemistry, American Chemical Society, Chicago, IL, August 1993; American Chemical Society: Washington, DC, 1993.
18. (b) Nørskov, J. K.; Clausen, B. S.; Topsøe, H. Catal. Lett. 1992, 13, 1.
19. (c) Byskov, L. S.; Hammer, B.; Nørskov, J. K.; Clausen, B. S.; Topsøe, H. Catal. Lett. 1997, 47, 177.
20. Huntley, D. R.; Mullins, D.; Wingeier, M. P. J. Phys. Chem. 1996, 100, 19620.
21. (a) Stöhr, J.; Kollin, E. B.; Fischer, D. A.; Hastings, J. B.; Zaera, F.; Sette, F. Phys. Rev. Lett. 1985, 55, 1468.
22. (b) Zaera, F.; Kollin, E. B.; Gland, J. L. Langmuir 1987, 3, 555.
23. (a) Wexler, R. M.; Tsai, M.-C.; Friend, C. M.; Muetterties, E. L. J. Am. Chem. Soc. 1982, 104, 2034.
24. (b) DiNardo, N. J.; Avouris, Ph.; Demuth, J. E. J. Chem. Phys. 1984, 81, 2169.
25. (c) Bridge, M. E.; Connolly, M.; Lloyd, D. R.; Somers, J.; Jakob, P.; Menzel, D. Spectrochim. Acta 1987, 43A, 1473.
26. (d) Rodriguez, J. A. Surf. Sci. 1992, 273, 385.
27. Huang, S. H.; Gland, J. L. J. Phys. Chem. 1996, 100, 2206.
28. Huang, S. H., Fischer, D. A.; Gland, J. In preparation.
29. Symposium on Modeling the Chemistry of Hydrotreating Processes. Chisholm, M. A., Ed.; Polyhedron 1997, 16, 3071-3246.
30. Zaera, F.; Kollin, E. B.; Gland, J. L. Surf. Sci. 1987, 184, 75.
31. Fulmer, J. P.; Zaera, F.; Tysoe, W. T. J. Phys. Chem. 1988, 92, 4147.
32. (a) Rodriguez, J. A. Surf. Sci. 1992, 278, 326.
33. (b) Jirsak, T.; Dvorak, J.; Rodriguez, J. A. J. Phys. Chem. B 1999, 103, 5550.
34. Roberts, J. T.; Friend, C. M. Surf. Sci. 1987, 186, 201.
35. Rodriguez-Arias, E. N.; Gainza, A. E.; Hernandez, A.; Lobos, P. S.; Ruette, F. J. Mol. Catal. A: Chem. 1995, 102, 163.
36. Ruette, F.; Valencia, N.; Sanchez-Delgado, R. A. J. Am. Chem. Soc. 1989, 111, 40.
37. Rodriguez, J. A.; Li, S. Y.; Hrbek, J.; Huang, H. H.; Xu, G.-Q. J. Phys. Chem. 1996, 100, 14476.
38. Rodriguez, J. A.; Li, S. Y.; Hrbek, J.; Huang, H. H.; Xu, G.-Q. Surf. Sci. 1997, 370, 85.
39. Li, S. Y.; Rodriguez, J. A.; Hrbek, J.; Huang, H. H.; Xu, G.-Q. Surf. Sci. 1996, 366, 29.
40. Kuhn, M.; Rodriguez, J. A. Surf. Sci. 1996, 355, 85.
41. Alstrup, I.; Chorkendorff, I.; Candia, R.; Clausen, B. S.; Topsøe, H. J. Catal. 1982, 77, 397.
42. Wagner, C. D.; Riggs, W. M.; Davis, L. E.; Moulder, J. F.; Muilenberg, G. E. Handbook of X-ray Photoelectron Spectroscopy; Perking-Elmer: Eden Prairie, MN, 1978; p 104.
43. Harris, S. Chem. Phys. 1982, 67, 229.
44. Wertheim, G. K.; DiSalvo, F. J.; Buchanan, D. N. E. Solid State Commun. 1973, 13, 1225.
45. Chen, J. G. Chem. Rev. 1996, 96, 1477.
46. Rodriguez, J. A.; Dvorak, J.; Capitano, A. T.; Gabelnick, A. M.; Gland, J. L. Surf. Sci. 1999, 429, L462.
47. Tarbuck, T. L.; McCrea, K. R.; Logan, J. W.; Heiser, J. L.; Bussell, M. E. J. Phys. Chem. B 1998, 102, 7845.
48. Salmeron, M.; Somorjai, G. A.; Wold, A.; Chianelli, R.; Liang, K. S. Chem. Phys. Lett. 1982, 90, 105.
49. Peterson, S. L.; Schulz, K. H. Langmuir 1996, 12, 941.
50. Li, S. Y.; Rodriguez, J. A.; Hrbek, J. To be published.
51. Papageorgopoulos, C.; Kamaratos, M. Surf. Sci. 1985, 164, 353.
52. HDS and HDN processes are typically carried out at temperatures between 400 and 600 K, which facilitate the intermixing of Ni and molybdenum sulfide.
53. Capitano, A.; Gland, J. L. J. Phys. Chem., submitted.
54. Hrbek, J.; van Campen, D. G.; Malik, I. J. J. Vac. Sci. Technol. A, 1995, 13, 1409.
55. (a) Wiegand, B. C.; Friend, C. M. Chem. Rev. 1992, 92, 491.
56. (b) Friend, C. M.; Chen, D. A. Polyhedron 1997, 16, 3165.
57. Quigley, W. C.; Yamamoto, H. D.; Aegerter, P. A.; Simpson, G. J.; Bussell, M. E. Langmuir 1996, 12, 1500.
58. (a) Petrakis, L.; Kiviat, F. E. J. Phys. Chem. 1976, 80, 606.
59. (b) Topsøe, N.-Y.; Topsøe, H.; Massoch, F. E. J. Catal. 1989, 119, 252
60. (c) Heinrich, V. E.; Cox, P. A. The Surface Science of Metal Oxides; Cambridge Press: New York, 1994.
61. To be published.
62. Chen, J.; Daniels, L. M.; Angelici, R. J. J. Am. Chem. Soc. 1991, 113, 2544.
63. Weller, K. J.; Fox, P. A.; Gray, S. D.; Wigley, D. E. Polyhedron 1997, 16, 3139.
64. Rodriguez, J. A. Polyhedron 1997, 16, 3177.