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Volumn 20, Issue 13, 1979, Pages 1141-1144

Solid state reactions of organopentafluorosilicates with copper(I) and copper(II) salts

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EID: 0011883997     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(01)86085-8     Document Type: Article
Times cited : (32)

References (21)
  • 5
    • 84914482438 scopus 로고    scopus 로고
    • K. Tamao, T. Kakui, and M. Kumada, Tetrahedron Lett., in press.
  • 6
    • 84914482437 scopus 로고    scopus 로고
    • K. Tamao, H. Matsumoto, T. Kakui, and M. Kumada, Tetrahedron Lett., submitted for publication.
  • 8
    • 84914482436 scopus 로고    scopus 로고
    • While the homo coupling occurred most efficiently with CuCl, the yield of the coupling product was very low with CuBr (e.g., 20% yield of 5,7-dodecadiene), and CuI did not induce the similar coupling reaction at all.
  • 9
    • 7044245151 scopus 로고
    • �ber Fluorchemie. XXVI. Darstellung von Butadien und Perfluorbutadien aus Vinyl- und Perfluorvinylpentafluorosilikaten
    • 4 on the corresponding vinyl- and perfluorovinylpentafluorosilicates in water:
    • (1970) Journal f�r Praktische Chemie , vol.312 , pp. 150
    • Mueller1    Dressler2    Dathe3
  • 10
    • 84914482435 scopus 로고    scopus 로고
    • For other methods for the preparation of symmetrical 1,3-dienes, see ref. 7 and references cited therein.
  • 11
    • 84914482434 scopus 로고    scopus 로고
    • 1H NMR, and MS spectral data. Such compounds may be formed by disproportionation between certain dissociated penta- or tetra-coordinate organofluorosilicon species at high temperatures, but the mechanism is not clear.
  • 12
    • 84914482433 scopus 로고    scopus 로고
    • 14 Products arising form the copper salt could not be characterized.
  • 19
    • 84984117448 scopus 로고
    • �ber Silikone CI. Eigenschaften und Reaktionen von Organopentafluorosilicaten
    • Mueller and his coworkers have briefly described that copper(II) salts are reduced to copper metal or copper(I) oxide by organosilicate producing “hydrocarbon product(s)”
    • (1965) Zeitschrift f�r anorganische und allgemeine Chemie , vol.341 , pp. 49
    • Mueller1    Dathe2
  • 20
    • 84914482431 scopus 로고    scopus 로고
    • The stoichiometry might be represented by the following equation, but this is only speculation at the present time.
  • 21
    • 84914482430 scopus 로고    scopus 로고
    • We thank the Grant-in-Aid for Scientific Research of the Ministry of Education (No. 303523), the Yamada Science Foundation, and Shin-etsu Chemical Co., Ltd. for support of the work.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.