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Volumn 17, Issue 6, 1998, Pages 1169-1176

Electrochemical and structural characterization of cis-and trans-[Cp(CO)Ru(μ-As(C6H5)2)]2, isomers that undergo two-electron-transfer oxidations

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EID: 0011833187     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9709998     Document Type: Article
Times cited : (9)

References (43)
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    • Theory for a completely reversible couple, 0.293 (Schwarz, W. M.; Shain, I. J. Phys. Chem. 1965, 69, 30); experiment for ferrocene under our conditions, 0.284.
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    • note
    • This demonstrates that the oxidation of 1 is a two-electron process if the diffusion coefficients of 1 and decamethylferrocene are similar.
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    • note
    • 2.
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    • For leading citations, see refs 5, 6, 10, and 14
    • For leading citations, see refs 5, 6, 10, and 14.
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    • note
    • fwd = 0.27 (5-s pulses); bulk coulometry, 1.9 F/equiv for 99% electrolysis (all data at Pt electrodes).
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    • 4, ΔG‡ = 0.38 eV (8.5 kcal/mol) at room temperature. For an introductory treatment of these concepts, see: Hale, J. M. In Reactions of Molecules at Electrodes; Hush, N. S. Ed.; Wiley-Interscience: London, 1971; p 229.
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