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Volumn 110, Issue 9, 1988, Pages 2800-2806

Preparation of a Thallium(I) Diazotate. Structure, Physicochemical Characterization, and Conversion to Novel N-Nitroso Compounds

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EID: 0011772111     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00217a018     Document Type: Article
Times cited : (20)

References (72)
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    • Azo and Diazo Chemistry
    • For pertinent reviews, see Aliphatic and Aromatic Compounds; Interscience: New York
    • For pertinent reviews, see:(a) Zollinger, H. Azo and Diazo Chemistry. Aliphatic and Aromatic Compounds; Interscience: New York, 1961.
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  • 3
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    • The Chemistry of Open-Chain Organic Nitrogen Compounds
    • Benjamin: New York
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    • (1965) , vol.1
    • Smith, P.A.S.1
  • 6
    • 0003784472 scopus 로고
    • The Chemistry of Amino, Nitroso and Nitro Compounds and Their Derivatives
    • Wiley: New York Part 2
    • Patai, S., Ed. The Chemistry of Amino, Nitroso and Nitro Compounds and Their Derivatives; Wiley: New York, 1982; Part 2.
    • (1982)
    • Patai, S.1
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    • European Patent Application EP 182 277
    • Baker, D. C. European Patent Application EP 182 277; Chem. Abstr. 1986, 105, 97502.
    • (1986) Chem. Abstr. , vol.105 , pp. 97502
    • Baker, D.C.1
  • 28
    • 0002624810 scopus 로고
    • Chemical Carcinogens
    • Searle, C. E., Ed.; ACS Monograph 182; American Chemical Society Washington, DC
    • Preussmann, R.; Stewart, B. W. In Chemical Carcinogens; Searle, C. E., Ed.; ACS Monograph 182; American Chemical Society: Washington, DC, 1984; pp 643–868.
    • (1984) , pp. 643-868
    • Preussmann, R.1    Stewart, B.W.2
  • 29
    • 0001421478 scopus 로고
    • Searle, C. E., Ed.; ACS Monograph 182; American Chemical Society: Washington, DC
    • Zedeck, M. S. In Chemical Carcinogens; Searle, C. E., Ed.; ACS Monograph 182; American Chemical Society: Washington, DC, 1984; pp 915–944.
    • (1984) Chemical Carcinogens , pp. 915-944
    • Zedeck, M.S.1
  • 44
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    • This author considered the mechanism by which alkylhydrazines are converted to diazotates by alkyl nitrites in base to involve sequential nitrosation, first of the secondary nitrogen atom and then of the primary amino group. Subsequent removal of the remaining N-H proton by added alkoxide was postulated to produce an anion capable of fragmenting to nitrous oxide and alkanediazotate. In support of this hypothesis, Thiele found that N-alkyl-N-nitrosohydrazines were converted to the same diazotates by treatment with only 1 mol each of nitrosating agent and base
    • Thiele, J. Justus Liebigs Ann. Chem. 1910, 376, 239–268. This author considered the mechanism by which alkylhydrazines are converted to diazotates by alkyl nitrites in base to involve sequential nitrosation, first of the secondary nitrogen atom and then of the primary amino group. Subsequent removal of the remaining N-H proton by added alkoxide was postulated to produce an anion capable of fragmenting to nitrous oxide and alkanediazotate. In support of this hypothesis, Thiele found that N-alkyl-N-nitrosohydrazines were converted to the same diazotates by treatment with only 1 mol each of nitrosating agent and base.
    • (1910) Justus Liebigs Ann. Chem. , vol.376 , pp. 239-268
    • Thiele, J.1
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    • Suhr, H. Chem. Ber. 1963, 96, 1720–1725.
    • (1963) Chem. Ber. , vol.96 , pp. 1720-1725
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    • and previous references in this series.
    • Moss, R. A.; Matsuo, M. J. Am. Chem. Soc. 1977, 99, 1643–1645, and previous references in this series.
    • (1977) J. Am. Chem. Soc , vol.99 , pp. 1643-1645
    • Moss, R.A.1    Matsuo, M.2
  • 72
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    • ORTEP, a FORTRAN Thermal Ellipsoid Plot Pro-gram for Crystal Structure Illustrations
    • Report ORNL-3794; Oak Ridge National Laboratory Oak Ridge, TN
    • Johnson, C. K. ORTEP, a FORTRAN Thermal Ellipsoid Plot Pro-gram for Crystal Structure Illustrations, Report ORNL-3794; Oak Ridge National Laboratory: Oak Ridge, TN, 1965.
    • (1965)
    • Johnson, C.K.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.