Extended irreversible thermodynamics of chemically reacting systems

Journal of Physical Chemistry B

Volumn 103, Issue 5, 1999, Pages 860-867

  Fort, J ^a   Casas Vazquez J ^b   Mendez V ^b  

^a UNIVERSITY OF GIRONA   (Spain)

^b UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0011684092     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp983134w     Document Type: Article

References (38)

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34. We would like to stress that, both in chemical reactions and heat conduction, there is no conflict between this conclusion and the specific form of evolution equations, which will in general depend on the microscopic (or phenomenological) approach used. We have mentioned in section 1 that the Grad method has not been yet applied to the explicit determination of the distribution functions in chemically reacting systems with inclusion of the reverse reactions. It is tempting to expect that such an analysis would lead to an evolution equation of the Maxwell-Cattaneo type. In such a case, the conclussion reached here that the nonequilibrium contribution to the specific entropy is quadratic in the reaction rate would be extended to systems for which the term containing the reaction rate time derivative in such a Maxwell-Cattaneo equation might be of importance.
35. Fort, J. Unpublished.
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