Metal hydrides as intermediates in the reactions of coordinated unsaturated hydrocarbons: Formation of propyne by protonation of trans-[WH(η3-C3H5)(Ph2PCH 2CH2PPh2)2]

Inorganica Chimica Acta

Volumn 259, Issue 1-2, 1997, Pages 107-117

  Henderson, Richard A ^a   Hughes, David L ^a   Macdonald, Colin J ^a   Oglieve, Kay E ^a  

^a NORWICH RESEARCH PARK   (United Kingdom)

Author keywords

Allyl complexes; Crystal structures; Hydride complexes; Tungsten complexes

Indexed keywords

ALIPHATIC COMPOUNDS; CHLORINE COMPOUNDS; COORDINATION REACTIONS; CRYSTAL STRUCTURE; CRYSTALS; HYDRIDES; METALS; PROPYLENE; PROTONATION; REACTION INTERMEDIATES;

ALLYL COMPLEXES; CO-ORDINATIVELY UNSATURATED; HYDRIDE COMPLEXES; OCTAHEDRAL GEOMETRY; TIME-COURSE EXPERIMENTS; TUNGSTEN COMPLEX; UNSATURATED HYDROCARBONS; X RAY CRYSTAL STRUCTURES;

TUNGSTEN COMPOUNDS;

EID: 0011591240     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0020-1693(96)05588-0     Document Type: Article

References (25)

1. D.J. Evans, R.A. Henderson and B.E. Smith in J. Reedijk (ed.), Bioinorganic Catalysis, Marcel Dekker, New York, 1993, p. 89.
2. J.J.R. Frausto da Silva, M.F.C. Guedes da Silva, R.A. Henderson, A.J.L. Pombeiro and R.L. Richards, J. Organomet. Chem., 461 (1993) 141.
3. R.A. Henderson, A.J.L. Pombeiro, R.L. Richards, J.J.R. Frausto da Silva and Y. Wang, J. Chem. Soc., Dalton Trans., (1995) 1193, and Refs. therein.
4. R.A. Henderson, J. Chem. Soc., Dalton Trans., (1995) 503, and Refs. therein.
5. R.A. Henderson, Angew. Chem., Int. Ed. Engl., 35 (1996) 946.
6. R.A. Henderson and K.E. Oglieve, J. Chem. Soc., Chem. Commun., (1991) 584.
7. K.E. Oglieve and R.A. Henderson, J. Chem. Soc., Dalton Trans., (1991) 3295.
8. K.E. Oglieve and R.A. Henderson, J. Chem. Soc., Chem. Commun., (1993) 474.
9. E.A. Allen, B.J. Brisdon and G.W.A. Fowles, J. Chem. Soc., (1964) 4531.
10. J.W. Byrne, H.U. Blaser and J.A. Osborne, J. Am. Chem. Soc., 97 (1975) 3871.
11. J.R. Dilworth and R.L. Richards, Inorg. Synth., 20 (1980) 119.
12. R.A. Henderson, J. Chem. Soc., Dalton Trans., (1982) 917.
13. J.H. Espenson, Chemical Kinetics and Reaction Mechanisms, McGraw-Hill, New York, 1981, p. 30.
14. R.A. Henderson and K.E. Oglieve, J. Chem. Soc., Dalton Trans., (1993) 3431.
15. G.M. Sheldrick, SHELX, program for crystal structure determination, University of Cambridge, UK, 1976; also an extended version, SHELXN, 1977.
16. G.M. Sheldrick, SHELX, program for crystal structure determination, University of Cambridge, UK, 1976; also an extended version, SHELXN, 1977.
17. International Tables for X-ray Crystallography, Vol. 4, Kynoch Press, Birmingham, UK, 1974, pp. 99, 149.
18. S.N. Anderson, R.L. Richards and D.L. Hughes, J. Chem. Soc., Dalton Trans., (1986) 245.
19. J. Chatt, G.A. Heath and R.L. Richards, J. Chem. Soc., Dalton Trans., (1974) 2074.
20. R.A. Henderson, unpublished work.
21. F.A. Cotton and R.L. Luck, Inorg. Chem., 28 (1989) 3210.
22. A.G. Orpen, L. Brammer, F.H. Allen, O. Kennard, D.C. Watson and R. Taylor, J. Chem. Soc., Dalton Trans., (1989) 51.
23. M. Nardelli, G. Pelizzi and G. Predieri, Gazz. Chim. Ital., 110 (1980) 375.
24. A. Hills, D.L. Hughes, C.J. Macdonald, Y. Mohammed and C.J. Pickett, J. Chem. Soc., Dalton Trans., (1991) 121.
25. J.H. Espenson, Chemical Kinetics and Reaction Mechanisms, McGraw-Hill, New York, 1981, p. 55.