Metal complexes as host molecules: The X-ray crystal structure of [Mo{HB(3,5-Me2pz)3}(NO){1,3-O2-4-CH 2(C6H13)C6H2}] 4 · 2CH2Cl2

Polyhedron

Volumn 16, Issue 13, 1997, Pages 2329-2333

  Berridge, Timothy E ^a   Chen, Hongli ^a   Hamor, Thomas A ^a   Jones, Christopher J ^a  

^a UNIVERSITY OF BIRMINGHAM   (United Kingdom)

Author keywords

Cyclophane; Hydrogen bond; Inclusion compound; Molybdenum; Nitrosyl

Indexed keywords

EID: 0011583021     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0277-5387(96)00558-X     Document Type: Article

References (30)

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20. 1H NMR spectra were in accord with the formulations shown and the pattern of signals for 1 is consistent with the molybdenum atoms occupying adjacent rather than non-adjacent sites in the rim of the calixresorcinarene.
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22. -1, λ = 0.71069 Å. The structure was determined [9] by direct methods and refined [10] by least-squares using anisotropic thermal parameters for all the nonhydrogen atoms, except for the outer five atoms of the four hexyl side chains. These atoms were located with some difficulty from Fourier difference syntheses and included in the refinement with
23. -3. We attribute the relatively high value of the discrepancy factors to the difficulty of modelling the hexyl chains, which may be affected by disorder.
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