Aminomethylene complexes of molybdenum(IV) and tungsten(IV) bearing 1,2-dithiolato ligands

Journal of Organometallic Chemistry

Volumn 617-618, Issue , 2001, Pages 656-670

  Filippou, Alexander C ^a   Portius, Peter ^a   Jankowski, Christel ^a  

^a HUMBOLDT UNIVERSITY   (Germany)

Author keywords

1,2 Dithiolato ligands; Carbene complexes; Carbyne complexes; Cyclopentadienyl complexes; Molybdenum; Tungsten

Indexed keywords

STAPHYLOCOCCUS PHAGE 3A;

EID: 0011551522     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(00)00701-4     Document Type: Article

References (73)

1. 3). Following this formalism Fischer-type Group 6 metal carbene and carbyne complexes have the metal center in the oxidation state 0, Schrock-type Group 6 metal carbene complexes have the metal center in the oxidation state +IV, and Schrock-type Group 6 metal carbyne complexes have the metal center in the oxidation state +II.
2. (a) B. Cetinkaya, M.F. Lappert, K. Turner, J. Chem. Soc. Chem. Commun. (1972) 851.
3. (b) C.W. Fong, G. Wilkinson, J. Chem. Soc. Dalton Trans. (1975) 1100.
4. (c) A.J. Hartshorn, M.F. Lappert, K. Turner, J. Chem. Soc. Dalton Trans. (1978) 348.
5. (d) R. Imwinkelried, L.S. Hegedus, Organometallics 7 (1988) 702.
6. (e) M.A. Schwindt, T. Lejon, L.S. Hegedus, Organometallics 9 (1990) 2814.
7. (f) J. Schubert, S. Mock, U. Schubert, Chem. Ber. 126 (1993) 657.
8. (g) M. Duetsch, F. Stein, A. de Meijere, Tetrahedron Lett. 34 (1993) 5875.
9. Hegedus L.S., de Weck G., D'Andrea S. J. Am. Chem. Soc. 110:1988;2122.
10. (a) C. Borel, L.S. Hegedus, J. Krebs, Y. Satch, J. Am. Chem. Soc. 109 (1987) 1101.
11. (b) L.S. Hegedus, S. D'Andrea, J. Org. Chem. 53 (1988) 3113.
12. (c) L.S. Hegedus, R. Imwinkelried, M. Alarid-Sargent, D. Dvorak, Y. Satoh, J. Am. Chem. Soc. 112 (1990) 1109.
13. (d) M.A. Schwindt, J.R. Miller, L.S. Hegedus, J. Organomet. Chem. 413 (1991) 143.
14. (e) Y. Narukawa, K.N. Juneau, D. Snustad, D.B. Miller, L.S. Hegedus, J. Org. Chem. 57 (1992) 5453.
15. (f) B. Alcaide, G. Dominguez, J. Plumet, M.A. Sierra, J. Org. Chem. 57 (1992) 447.
16. (g) M. Es-Sayed, T. Heiner, A. de Meijere, Synlett (1993) 57.
17. (h) B. Ronan, L.S. Hegedus, Tetrahedron, 49 (1993) 5549.
18. Söderberg B.C., Hegedus L.S. J. Org. Chem. 56:1991;2209.
19. (a) L.S. Hegedus, E. Lastra, Y. Narukawa, D.C. Snustad, J. Am. Chem. Soc. 114 (1992) 2991.
20. (b) L.S. Hegedus, Acc. Chem. Res. 28 (1995) 299.
21. (a) B. Denise, R. Goumont, A. Parlier, H. Rudler, J.-C. Daran, J. Vaissermann, J. Organomet. Chem. 377 (1989) 89.
22. (b) B. Denise, R. Goumont, A. Parlier, H. Rudler, J.-C. Daran, J. Vaissermann, J. Chem. Soc. Chem. Commun. (1990) 1238.
23. (c) B.A. Anderson, W.D. Wulff, A.L. Rheingold, J. Am. Chem. Soc. 112 (1990) 8615.
24. (d) H. Rudler, A. Parlier, R. Goumont, J.-C. Daran, J. Vaissermann, J. Chem. Soc. Chem. Commun. (1991) 1075.
25. (e) E. Chelain, R. Goumont, L. Hamon, A. Parlier, M. Rudler, H. Rudler, J.-C. Daran, J. Vaissermann, J. Am. Chem. Soc. 114 (1992) 8088.
26. (f) A. Parlier, M. Rudler, H. Rudler, R. Goumont, J.-C. Daran, J. Vaissermann, Organometallics 14 (1995) 2760.
27. (g) H. Rudler, A. Parlier, M. Rudler, J. Vaissermann, J. Organomet. Chem. 567 (1998) 101.
28. Sierra M.A., Soderberg B., Lander P.A., Hegedus L.S. Organometallics. 12:1993;3769.
29. A.C. Filippou, D. Wössner, B. Lungwitz, G. Kociok-Köhn, Angew. Chem. 108 (1996) 981; Angew. Chem. Int. Ed. Engl. 35 (1996) 876.
30. A.C. Filippou, D. Wössner, B. Lungwitz, G. Kociok-Köhn, Angew. Chem. 108 (1996) 981; Angew. Chem. Int. Ed. Engl. 35 (1996) 876.
31. Kreissl F.R., Sieber W.J., Wolfgruber M. J. Organomet. Chem. 270:1984;C45.
32. (a) B. Lungwitz, A.C. Filippou, Transition Metal Carbyne Complexes, Kluwer Academic Publishers, NATO ACS Series C, vol. 392, 1993, p. 249.
33. (b) W. Grünleitner, Dissertation, Technische Universität München, 1991.
34. Cook D.J., Hill A.F. Organometallics. 16:1997;5616.
35. A.C. Filippou, B. Lungwitz, G. Kociok-Köhn, Eur. J. Inorg. Chem. (1999) 1905.
36. Brandts J.A.M., Kruiswijk E., Boersma J., Spek A.L., van Koten G. J. Organomet. Chem. 585:1999;93.
37. Filippou A.C., Grünleitner W., Fischer E.O., Imhof W., Huttner G. J. Organomet. Chem. 413:1991;165.
38. Filippou A.C., Grünleitner W. Z. Naturforsch. B44:1989;1572.
39. A.C. Filippou, P. Portius, D. Neumann, B. Lungwitz, unpublished results.
40. For high oxidation state Group 6 metal aminocarbyne complexes bearing carbonyl ligands see also: (a) A.C. Filippou, E.O. Fischer, J. Okuda, J. Organomet. Chem. 339 (1988) 309.
41. (b) A.C. Filippou, E.O. Fischer, ibid. 341 (1988) C35.
42. (c) A.C. Filippou, E.O. Fischer, H.G. Alt, ibid. 344 (1988) 215.
43. (d) A.C. Filippou, E.O. Fischer, R. Paciello, ibid. 347 (1988) 127.
44. (e) A.C. Filippou, E.O. Fischer, ibid. 349 (1988) 367.
45. (f) A.C. Filippou, Polyhedron 8 (1989) 1285.
46. (g) A.C. Filippou, E.O. Fischer, J. Organomet. Chem. 382 (1990) 143.
47. (h) A.C. Filippou, E.O. Fischer, W. Grünleitner, ibid. 386 (1990) 333.
48. (i) A.C. Filippou, W. Grünleitner, C. Völkl, P. Kiprof, Angew. Chem. 103 (1991) 1188; Angew. Chem. Int. Ed. Engl. 30 (1991) 1167.
49. (i) A.C. Filippou, W. Grünleitner, C. Völkl, P. Kiprof, Angew. Chem. 103 (1991) 1188; Angew. Chem. Int. Ed. Engl. 30 (1991) 1167.
50. (j) A.C. Filippou, W. Grünleitner, J. Organomet. Chem. 407 (1991) 61.
51. (k) A.C. Filippou, B. Lungwitz, K.M.A. Wanninger, E. Herdtweck, Angew. Chem. 107 (1995) 1007; Angew. Chem. Int. Ed. 34 (1995) 924.
52. (k) A.C. Filippou, B. Lungwitz, K.M.A. Wanninger, E. Herdtweck, Angew. Chem. 107 (1995) 1007; Angew. Chem. Int. Ed. 34 (1995) 924.
53. Fischer H., Hofmann P., Kreißl F.R., Schrock R.R., Schubert U., Weiss K. Carbyne Complexes. 1988;VCH, Weinheim.
54. (a) M.H. Chisholm, B.K. Conroy, J.C. Huffman, N.S. Marchant, Angew. Chem. 98 (1986) 448; Angew. Chem. Int. Ed. Engl. 25 (1986) 446.
55. (a) M.H. Chisholm, B.K. Conroy, J.C. Huffman, N.S. Marchant, Angew. Chem. 98 (1986) 448; Angew. Chem. Int. Ed. Engl. 25 (1986) 446.
56. (b) M.H. Chisholm, J.C. Huffman, N.S. Marchant, J. Chem. Soc. Chem. Commun. (1986) 717.
57. (c) M.H. Chisholm, D. Ho, J.C. Huffman, N.S. Marchant, Organometallics 8 (1989) 1626.
58. (a) P. Kubacek, R. Hoffman, Z. Havlas, Organometallics 1 (1982) 180.
59. (b) E.L. Muetterties, J.R. Bleeke, E.J. Wucherer, T.A. Albright, Chem. Rev. 82 (1982) 499.
60. (c) R. Poli, Organometallics 9 (1990) 1892.
61. Sandorfy C. Patai S., The Chemistry of the Carbon-Nitrogen Double Bond. 1970;Interscience, London.
62. Filippou A.C., Hofmann P., Kiprof P., Schmidt H.R., Wagner C. J. Organomet. Chem. 459:1993;233.
63. 1H-NMR spectra of 3a and 3b at 222 K and of 9a at 298 K.
64. Nugent W.A., Mayer J.M. Metal-Ligand Multiple Bonds. 1988;Wiley, New York.
65. A.C. Filippou, J.G. Winter, unpublished results.
66. Structural information on aminomethylene complexes is very rare: A CSD-search showed that no other crystal structures have been reported so far.
67. Dötz K.H., Fischer H., Hofmann P., Kreissl F.R., Schubert U., Weiss K. Transition Metal Carbene Complexes. 1983;VCH, Weinheim.
68. Lucas H.J., Kennedy E.R. Org. Synth. Collect. Index. 3:1976;482.
69. Bähr G., Schleitzer G. Chem. Ber. 90:1957;438.
70. I. Degani, R. Fochi, Synthesis (1976) 471.
71. (a) A. L. Spek, PLUTON-92, PLUTON-93, graphics program, University of Utrecht, Netherlands, 1992 and 1993.
72. (b) A.L. Spek, Acta Crystallogr. Sect. A 46 (1990) C34.
73. L. Zsolnai, H. Pritzkow, ZORTEP, ORTEP program for PC, Universität Heidelberg, Germany, 1994.