Hydrological and soil geochemical controls of the abundance and fractionation patterns of rare earth elements in a periodically acidic Boreal stream

Geochemistry: Exploration, Environment, Analysis

Volumn 1, Issue 2, 2001, Pages 101-108

  Åström, Mats ^a  

^a ÅBO AKADEMI UNIVERSITY   (Finland)

Author keywords

Acid soil; Acidification; Hydrology; Rare earth elements; REE; Stream; Sulphate

Indexed keywords

ACIDIFICATION; CATCHMENTS; EXPLORATORY GEOCHEMISTRY; FLOW OF WATER; GADOLINIUM; HYDROLOGY; RARE EARTH ELEMENTS; RARE EARTHS; RUNOFF; SEDIMENTS; SHALE; SUBMARINE GEOLOGY; SULFUR COMPOUNDS;

ACID SOILS; ACID SULPHATE SOILS; FIRST-ORDER STREAMS; FRACTIONATION PATTERNS; GEOCHEMICAL CONTROL; RARE EARTH ELEMENTS (REES); STREAM; SULPHATES;

SOILS;

EID: 0011240508     PISSN: 14677873     EISSN: None     Source Type: Journal    
DOI: 10.1144/geochem.1.2.101     Document Type: Article

References (47)

1. ÅSTRÖM, M. 1998. Partitioning of transition metals in oxidised and reduced zones of sulphide-bearing fine-grained sediments. Applied Geochemistry, 13, 607-617.
2. ÅSTRÖM, M. 2001a. The effect of acid soil leaching on trace element abundance in a medium-sized stream, W. Finland. Applied Geochemistry, 16, 387-396.
3. ÅSTRÖM, M. 2001b. Abundance and fractionation patterns of rare earth elements in streams affected by acid sulphate soils. Chemical Geology, in press.
4. ÅSTRÖM, M. & BJÖRKLUND, A. 1995. Impact of acid sulfate soils on stream water geochemistry in western Finland. Journal of Geochemical Exploration, 55, 163-170.
5. ÅSTRÖM, M. & BJÖRKLUND, A. 1996. Hydrogeochemistry of a stream draining sulfide-bearing postglacial sediments in Finland. Water, Air and Soil Pollution, 89, 233-246.
6. ÅSTRÖM, M. & BJÖRKLUND, A. 1997. Geochemistry and acidity of sulphide-bearing postglacial sediments of western Finland. Environmental Geochemistry and Health, 19, 155-164.
7. BANKS, D., HALL, G., REIMANN, C & SIEWERS, C. 1999. Distribution of rare earth elements in crystalline bedrock groundwaters: Oslo and Bergen regions, Norway. Applied Geochemistry, 14, 27-39.
8. BAU, M. 1999. Scavenging of dissolved yttrium and rare earth elements by precipitating iron oxyhydroxide: Experimental evidence for Ce oxidation, Y-Ho fractionation and lanthanide tetrad effect. Geochimica et Cosmochimica Acta, 63, 67-77.
9. BYRNE, R. H. & LI, B. 1995. Comparative complexation behavior of the rare earths. Geochimica et Cosmochimica Acta, 59, 4575-4589.
10. CANTRELL, K. J. & BYRNE, R. H. 1987. Rare earth element complexation by carbonate and oxalate ions. Geochimica et Cosmochimica Acta, 51, 597-605.
11. DENG, H., ÅSTRÖM, M. & BJÖRKLUND, A. 1998. Geochemical and mineralogical properties of sulfide-bearing fine-grained sediments in Finland. Environmental Geology, 36, 37-44.
12. ELDERFIELD, H., UPSTILL-GODDARD, R. & SHOLKOVITZ, E. R. 1990. The rare earth elements in rivers, estuaries and coastal seas and their significance to the composition of ocean waters. Geochimica et Cosmochimica Acta, 54, 971-991.
13. GOLDSTEIN, S. J. & JACOBSEN, S. B. 1988. Rare earth elements in river waters. Earth and Planetary Science Letters, 89, 35-47.
14. GOSSELIN, D. C., SMITH, M. R., LEPEL, A. E. & LAUL, J. C. 1992. Rare earth elements in chloride-rich groundwarer, Palo Duro Basin, Texas, USA. Geochimica et Cosmochimica Acta, 56, 1495-1505.
15. GROMET, L. P., DYMEK, R. F., HASKIN, L. A. & KOROTEV, R. L. 1984. The 'North American Shale composite': Its compilation, major and trace element characteristics. Geochimica et Cosmochimica Acta, 48, 2469-2482.
16. HARTIKAINEN, H. & YLI-HALLA, M. 1986. Oxidation-induced leaching of sulphate and cations from acid sulphate soils. Water, Air and Soil Pollution, 27, 1-13.
17. HASKIN, L. A., HASKIN, M. A., FREY, F. A. & WILDERMAN, T. R. 1968. Relative and absolute terrestrial abundances of the rare earths. In Ahrens, L. H. (ed.) Origin and Distribution of the Elements. Pergamon, Oxford, 889-912.
18. HOYLE, J., ELDERFIELD, H., GLEDHILL, A. & GREAVES, M. 1984. The behaviour of the rare earth elements during mixing of river and sea waters. Geochimica et Cosmochimica Acta, 48, 143-149.
19. INGRI, J., WIDERLUND, A., LAND, M., GUSTAFSSON, Ö., ANDERSSON, P. & ÖHLANDER, B. 2000. Temporal vanations in the fractionation of rare earth elements in a boreal river, he role of colloidal particles. Chemical Geology, 166, 23-45.
20. JOHANNESSON, K. H. & LYONS, W. B. 1995. Rare-earth element geochemistry of Colour Lake, an acidic freshwater lake on Axel Heiberg Island, Northwest territories, Canada. Chemical Geology, 119, 209-223.
21. JOHANNESSON, K. H. & ZHOU, X. 1999. Origin of middle rare earth element enrichments in acid waters of a Canadian high arctic lake. Geochimica et Cosmochimica Acta, 63, 153-165.
22. JOHANNESSON, K. H., STETZENBACH, K. J. & HODGE, V. F. 1997. Rare earth elements as geochemical tracers of regional groundwater mixing. Geochimica et Cosmochimica Acta, 61, 3605-3618.
23. 3 in limiting dissolved rare earth concentrations: A review of recent information. Aquatic Geochemistry, 1, 157-173.
24. JOHANNESSON, K. H., LYONS, W. B., YELKEN, M. A., GAUDETTE, H. E. & STETZENBACH, K. J. 1996. Geochemistry of the rare-earth elements in hypersaline and dilute acidic natural waters: Complexation behaviour and middle rare-earth element enrichments. Chemical Geology, 133, 125-144.
25. KEASLER, K. M. & LOVELAND, W. D. 1982. Rare earth elemental concentrations in some Pacific northwest rivers. Earth and Planetary Science Letters, 61, 68-72.
26. LAHERMO, P., VÄÄNÄNEN, P., TARVAINEN, T. & SALMINEN, R. 1996. Geochemical Atlas of Finland part 3: Environmental Geochemistry - stream waters and sediments. Geological Survey of Finland, Esbo, Finland.
27. LAND, M., ÖHLANDER, B., INGRI, J. & THUNBERG, J. 1999. Solid speciation and fractionation of rare earth elements in a spodosol profile from northern Sweden as revealed by sequential extraction. Chemical Geology, 160, 121-138.
28. LI, B. & BYRNE, R. H. 1997. Ionic strength dependence of rare earth-NTA stability constants at 25C. Aquatic Geochemistry, 3, 99-115.
29. LOWSON, R. T. 1982. Aqueous oxidation of pyrite by molecular oxygen. Chemical Reviews, 82, 461-497.
30. MILLERO, F. J. 1992. Stability constants for the formation of rare earth inorganic complexes as a function of ionic strength. Geochimica et Cosmochimica Acta, 56, 3123-3132.
31. ÖBORN, I. 1991. Some effects of chemical weathering in three cultivated acid sulfate soils in Sweden. In: Wright, R. J., Baligar, V. C. & Murrmann, R. P. (eds) Plant-soil interactions at low pH. Developments in Plant and Soil Sciences, 45, 55-63.
32. ÖHLANDER, B., LAND, M., INGRI, J. & WIDERLUND, A. 1996. Mobility of rare earth elements during weathering of till in northern Sweden. Applied Geochemistry, 11, 93-99.
33. PALKO, J. 1994. Acid sulphate soils and their agricultural and environmental problems in Finland. PhD Thesis, University of Oulu, Finland.
34. PUROKOSKI, P. 1958. Die schwefelhaltigen tonsedimente in dem flachlandgebiet von Liminka im lichte chemischer forschung. Agrogeologische Publicatioiten (Helsinki), 70, 1-71.
35. 3 at 25°C. Journal of Solution Chemistry, 19, 525-541.
36. SHOLKOVITZ, E. R. 1992. Chemical evolution of rare earth elements: fractionation between colloidal and solution phases of filtered river water. Earth and Planetary Science Letters, 114, 77-84.
37. SHOLKOVITZ, E. R. 1995. The aquatic geochemistry of rare earth elements in rivers and estuaries. Aquatic Geochemistry, 1, 1-34.
38. SHOLKOVITZ, E. R., LANDING, W. M. & LEWIS, B. L. 1994. Ocean particle chemistry: the fractionation or rare earth elements between suspended particles and seawater. Geochimica et Cosmochimica Acta, 58, 1567-1579.
39. SMEDLEY, P. L. 1991. The geochemistry of rare earth elements in groundwater from the Carnmenellis area, southwest England. Geochimica et Cosmochimica Acta, 55, 2767-2779.
40. WEPPLING, K. 1993. Hydrochemical factors affecting the neutralization demand in acid sulphate waters. Vatten, 49, 161-170.
41. WHEELWRIGHT, E. J., SPEDDING, F. H. & SCHWARZENBACH, G. 1953. The stability of the rare earth complexes with EDTA. Journal of the American Chemical Society, 75, 4196-4201.
42. WIKLANDER, L. & HALLGREN, G. 1949. Studies on gyttja soils: Distribution of different sulfur and phosphrous forms and of iron, manganese and calcium carbonate in a profile from Kungsängen. The Annals of the Royal Agricultural College of Sweden, 16, 811-827.
43. WIKLANDER, L., HALLGREN, G. &JONSSON, E. 1950. Studies on gyttja soils: rate of sulfur oxidation. The Annals of the Royal Agricultural College of Sweden, 17, 425-440.
44. WOOD, S. A. 1990. The aqueous geochemistry of the rare-earth elements and yttrium. Chemical Geology, 82, 159-186.
45. YLI-HALLA, M. 1997. Classification of acid sulphate soils in Finland according to Soil Taxonomy and the FAO/Unesco legend. Agricultural and food science in Finland, 6, 247-258.
46. YLI-HALLA, M., PUUSTINEN, M. & KOSKIAHO, J. 1999. Area of cultivated acid sulfate soils in Finland. Soil Use and Management, 15, 62-67.
47. ZHANG, C., WANG, L. & ZHANG, S. 1998. Geochemistry of rare earth elements in the mainstream of the Yangtze river, China. Applied Geochemistry, 13, 451-462.