Electron Self-Exchange Kinetics for a Water-Soluble Ferrocenium/Ferrocene Couple: Rate Modulation via Charge Dependent Calix[6]arene-p-sulfonate Encapsulation

Inorganic Chemistry

Volumn 35, Issue 5, 1996, Pages 1402-1404

  Nielson, Roger M ^a,b   Hupp, Joseph T ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

^b SOUTHERN OREGON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0011231293     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic951191n     Document Type: Article

References (18)

1. Todd, M. D.; Dong, Y.; Hupp, J. T. Inorg. Chem. 1991, 30, 4685.
2. Nielson, R. M.; Yoon, D. I.; Hupp, J. T. J. Am. Chem. Soc. 1995, 117, 9085.
3. Nielson, R. M., Hupp, J. T. Inorg. Chem., in press.
4. See also: (a) Imonigie, J. A.; Macartney, D. H. Inorg. Chem. 1993, 32, 1007. (b) Imonigie, J. A.; Macartney, D. H. J. Chem. Soc., Dalton Trans. 1993, 1830. (c) Johnson, M. D.; Reinsborough, V. C.; Ward, S. Inorg. Chem. 1992, 31, 1085.
5. See also: (a) Imonigie, J. A.; Macartney, D. H. Inorg. Chem. 1993, 32, 1007. (b) Imonigie, J. A.; Macartney, D. H. J. Chem. Soc., Dalton Trans. 1993, 1830. (c) Johnson, M. D.; Reinsborough, V. C.; Ward, S. Inorg. Chem. 1992, 31, 1085.
6. See also: (a) Imonigie, J. A.; Macartney, D. H. Inorg. Chem. 1993, 32, 1007. (b) Imonigie, J. A.; Macartney, D. H. J. Chem. Soc., Dalton Trans. 1993, 1830. (c) Johnson, M. D.; Reinsborough, V. C.; Ward, S. Inorg. Chem. 1992, 31, 1085.
7. (a) Shinkai, S.; Mori, S.; Koreishi, H.; Tsubaki, T.; Manube, O. J. Am. Chem Soc. 1986, 108, 2409.
8. (b) Atwood, J. L.; Clark, D. L.; Juneja, R. K.; Orr, G. W.; Robinson, K. D.; Vincent, R. L. J. Am. Chem. Soc 1992, 114, 7558.
9. Zhang, L.; Macias, A.; Lu, T.; Gordon, J. I.; Gokel, G. W.; Kaifer, A. E. J. Chem. Soc., Chem. Commun. 1993, 1017.
10. Lindsay, J. K.; Hauser, C R. J Org. Chem. 1957, 22, 355.
11. See, for example: Chan, M. S.; Wahl, A. C J. Phys. Chem 1978, 82, 2542.
12. 1, = 80 mV (23-fold increase in K).
13. -1 or less.
14. n- also must exist, but should be of negligible significance under our conditions.
15. n-] using Mathsoft, Plus (Mathsoft. Inc.. 1994).
16. c with changes in ionic strength (changes in calixarene concentration).
17. The data in Figure 2 were fit to eq 5b by using Microcal Origin 2.8 (Microcal Software, Inc., 1993).
18. +, but should be more important for the latter