Facile Electrophllic Halogen Exchange between Boron Trlhalides and Transltlon-Metal Perfluoroalkyl Complexes. A Novel Method for the Synthesis of Reactive Transltlon-Metal Haloalkyl Complexes

Organometallics

Volumn 2, Issue 8, 1983, Pages 1061-1062

  Richmond, Thomas G ^a   Shrlver, Duward F ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0011034349     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om50002a028     Document Type: Article

References (41)

1. Shriver, D.F. J. Organomet. Chem. 1975, 94, 259-271.
2. Shriver, D.F. Adv. Chem. Ser. 1981, No. 152, 1-18.
3. Butts, S.B.; Strauss, S.H.; Holt, E.M.; Stimson, R.E.; Alcock, N.W.; Shriver, D.F. J. Am. Chem. Soc. 1980,102, 5093-5100.
4. Richmond, T.G.; Basolo, F.; Shriver, D.F. Organometallics 1982, 12, 1624-1628.
5. Treichel, P.L.; Stone, F.G. A. Adv. Organomet. Chem. 1964, 1,143-220.
6. Bruce, M.I.; Stone, F.G. A. Prep. Inorg. React. 1968, 4, 177-235.
7. King, R.B. Acc. Chem. Res. 1970, 3, 417-427.
8. Mason, R.; Russell, D.R. Chem. Commun. 1965, 182-183.
9. Churchill, M.R. Inorg. Chem. 1965, 4, 1734-1739.
10. Churchill, M.R. Inorg. Chem. 1967, 6, 185-190.
11. Churchill, M.R.; Fennessey, J.R. Inorg. Chem. 1967, 6, 1213-1220.
12. Pitcher, E.; Stone, F.G. A. Spectrochim. Acta 1962, 18, 585-594.
13. King, R.B.; Bisnette, M.B. J. Organomet. Chem. 1964, 2, 15-37.
14. Cotton, F.A.; McCleverty, J.A. J. Organomet. Chem. 1965, 4, 490.
15. Cotton, F.A.; Wing, R.M. J. Organomet. Chem. 1967, 9, 511-517.
16. Graham, W.A.G. Inorg. Chem. 1968, 7, 315-321.
17. Hall, M.B.; Fenske, R.F. Inorg. Chem. 1972, 11, 768-775.
18. Reger, D.L.; Dukes, M.D. J. Organomet. Chem. 1978, 153, 67-72.
19. Clark, B.R.; Hoskins, S.V.; Roper, W.R. Organomet. Chem. 1982, 234, C9-C12.
20. An iridium trichloromethyl complex has been prepared: Dem-ming, A.J.; Shaw, B.L. J. Chem. Soc. A 1969, 1128-1134.
21. Transition-metal monochloromethyl complexes: Moss, J.R.; Pelling, S.J. Organomet. Chem. 1982, 236, 221-227 and references therein
22. Transition-metal chloromethyl complexes are not accessible by thermal or photochemical decarbonylation of chloroacetyl precursors: Dilgassa, M.; Curtis, M.D. J. Organomet. Chem. 1979,172, 177-184.
23. Main-group trihalogenomethyl complexes are well-known and synthetically useful: Seyferth, D. Acc. Chem. Res. 1972, 5, 65-74.
24. King, R.B. “Organometallic Syntheses”; Academic Press: New York, 1965; Vol. 1.
25. Quick, M.H.; Angelici, R.J. Inorg. Synth. 1979, 19, 161-163.
26. Onaka, S.J. Inorg. Nucl. Chem. 1974, 36, 1721-1724.
27. For example v(C-Cl) in CC13I is 755 cm-1: Nakamoto, K. “Infrared and Raman Spectra of Inorganic and Coordination Compounds”, 3rd ed.; Wiley-Interscience: New York, 1978; p 144.
28. Kaesz, H.D.; King, R.B.; Stone, F.G.A. Z. Naturforsch., B: Anorg. Chem., Org. Chem., Biochem., Biophys., Biol. 1960,15B, 763-764.
29. Muetterties, E.L. “The Chemistry of Boron and Its Compounds”; Wiley: New York, 1967; pp 13-14.
30. Tobey, S.W.; West, R.J. Am. Chem. Soc. 1964, 86, 1459.
31. Halogen exchange between BI3 and Cp2MCl2 (M = Ti, Zr, Hf) has also been reported: Druce, D.M.; Kingston, B.M.; Lappert, M.F.; Spalding, T.R.; Srivastava, R.C. J. Chem. Soc. A 1969, 2106-2110.
32. Noack, K.; Schaerer, U.; Calderazzo, F.J. Organomet. Chem. 1967 8 517-526
33. Piper, T.S.; Cotton, F.A.; Wilkinson, G.J. Inorg. Nucl. Chem. 1955,1,165-174.
34. Kristoff, J.S.; Shriver, D.F. Inorg. Chem. 1973,12, 1788-1793.
35. Gansow, O.A.; Schexnayder, D.A.; Kinura, B.Y. J. Am. Chem. Soc. 1972, 94, 3406-3408.
36. Kochhar, R.K.; Pettit, R.J. Organomet. Chem. 1966, 6, 272-278.
37. Johnson, B.V.; Ouseph, P.J.; Hsieh, J.S.; Steinmetz, A.L.; Shade, J.E. Inorg. Chem. 1979, 18, 1796-1799.
38. Clark, G.R.; Marsden, K.; Roper, W.R.; Wright, L.J. J. Am. Chem. Soc. 1980, 102, 1206-1207.
39. Clark, G.R.; Marsden, K.; Roper, W.R.; Wright, L.J. J. Am. Chem. Soc. 1980, 102, 6570-6571.
40. Roper, W.R.; Wright, A.H. J. Organomet. Chem. 1982, 233, C59-C63.
41. Mansuy, D. Pure Appl. Chem. 1980, 52, 681-690.