Conversion of trifluoromethyl-substituted π-vinylcarbeneiron to difluorotrimethylenemethane complexes

Chemistry Letters

Volumn , Issue 7, 1996, Pages 513-514

  Fujita, Ken Ichi ^a   Watanabe, Yoshihisa ^a   Mitsudo, Take Aki ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0010956096     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1996.513     Document Type: Article

References (14)

1. a) T. Mitsudo, H. Nakanishi, T. Inubushi, I. Morishima, Y. Watanabe, and Y. Takegami, J. Chem. Soc., Chem. Commun., 1976, 416.
2. b) T. Mitsudo, K. Fujita, S. Nagano, T. Suzuki, Y. Watanabe, and H. Masuda, Organometallics, 14, 4228 (1995).
3. c) T. Mitsudo, H. Watanabe, T. Sasaki, Y. Takegami, Y. Watanabe, K. Kafuku, and K. Nakatsu, Organometallics, 8, 368 (1989).
4. a) T. Valeri, F. Meier, and E. Weiss, Chem. Ber., 121, 1093 (1988).
5. b) A. Mayr, M. F. Asaro, and T. J. Glines, J. Am. Chem. Soc., 109, 2215 (1987).
6. c) K. E. Garrett, J. B. Sheridan, D. B. Pourreau, W. C. Feng, G. L. Geoffroy, D. L. Staley, and A. L. Rheingold, J. Am. Chem. Soc., 111, 8383 (1989).
7. d) S. G. Feng, A. S. Gamble, and J. L. Templeton, Organometallics, 8, 2024 (1989).
8. e) J. Park, S. Kang, D. Whang, and K. Kim, Organometallics, 11, 1738 (1992).
9. f) J. Barluenga, F. Aznar, A. Martin, S. G. Granda, and E. P. Carreno, J. Am. Chem. Soc., 116, 11191 (1994).
10. 4Fe: C, 32.96; H, 1.54; F, 28.96%.
11. w = 0.035.
12. M. D. Jones, R. D. W. Kemmitt in Advances in Organometallic Chemistry, Vol. 27 (Eds.: F. G. A. Stone, R. West), Academic Press, inc., London (1987), p. 279, and references therein.
13. 1J(C,H) = 161.1 Hz, CH).
14. For the anti to syn isomerization of π-allyl complexes, for example: R. W. Fish, W. P. Giering, D. Marten, and M. Rosenblum, J. Organomet. Chem., 105, 101 (1976).