Reactions of heterodinuclear Fe-Pt and Fe-Pd complexes with cyclic bis(amino)germylenes and -stannylenes: A bridging metal(II) amide unit between two different transition metal centers and donor stabilization of terminal germylene and stannylene ligands by Si(OMe)3

Organometallics

Volumn 15, Issue 18, 1996, Pages 3868-3875

  Knorr, Michael ^a   Hallauer, Eva ^a   Huch, Volker ^a   Veith, Michael ^a   Braunstein, Pierre ^b  

^a SAARLAND UNIVERSITY   (Germany)

^b UNIVERSITÉ DE STRASBOURG   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0010926074     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om960167u     Document Type: Article

References (43)

1. (a) Braunstein, P.; Knorr, M. In Metal Ligand Interactions; Russo, N., Salahub, D. R., Eds.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1995; p 49.
2. (b) Braunstein, P.; Knorr, M. In Organosilicon Chemistry II; Auner, N., Weis, J., Eds.; VCH: Weinheim, Germany, 1996; p 553.
3. (c) Braunstein, P.; Knorr, M.; Stahrfeldt, T. J. Chem. Soc., Chem. Commun. 1994, 1913.
4. (d) Braunstein, P.; Faure, T.; Knorr, M.; Stährfeldt, T.; DeCian, A.; Fischer, J. Gazz. Chim. Ital. 1995, 125, 35.
5. (e) Braunstein, P.; Morise, X.; Blin, J. J. Chem. Soc., Chem. Commun. 1995, 1455.
6. (f) Braunstein, P.; Knorr, M.; Hirle, B.; Reinhard, G.; Schubert, U. Angew. Chem., Int. Ed. Engt. 1992, 31, 1583.
7. (g) Braunstein, P.; Knorr, M. J. Organomet. Chem. 1995, 500, 21.
8. (h) Knorr, M.; Braunstein, P.; DeCian, A.; Fischer, J. Organometallics 1995, 14, 1302.
9. (i) Knorr, M.; Braunstein, P.; Tiripicchio, A.; Ugozzoli, F. Organometallics 1995, 14, 4910.
10. (j) Bodensieck, U.; Braunstein, P.; Deck, W.; Faure, T.; Knorr, M.; Stern, C. Angew. Chem., Int. Ed. Engt. 1994, 33, 2440.
11. (a) Veith, M. Angew. Chem. 1975, 87, 287.
12. (b) Veith, M.; Grosser, M. Z. Naturforsch. 1982, 37b, 1375.
13. (c) Veith, M.; Lange, H.; Bräuer, K.; Bachmann, R. J. Organomet. Chem. 1981, 216, 377.
14. (d) Veith, M.; Stahl, L.; Huch, V. Inorg. Chem. 1989, 28, 3278.
15. (e) Veith, M. Angew. Chem., Int. Ed. Engl. 1987, 26, 1.
16. (f) Veith, M.; Stahl, L.; Huch, V. J. Chem. Soc., Chem. Commun. 1990, 359.
17. (g) Veith, M.; Stahl, L.; Huch, V. Organometallics 1993, 12, 1914.
18. (h) Veith, M.; Stahl, L. Angew. Chem., Int. Ed. Engl. 1993, 32, 106.
19. (i) Veith, M.; Müller, A.; Stahl, L.; Nötzel, M.; Jarczyk, M.; Huch, V. Inorg. Chem. 1996, 35, 3848.
20. (a) Braunstein, P.; Knorr, M.; Tiripiechio, A.; Tiripicchio-Camellini, M. Angew. Chem., Int. Ed. Engl. 1989, 28, 1361.
21. (b) Knorr, M.; Faure, T.; Braunstein. P. J. Organomet. Chem. 1993, 447, C4.
22. (a) Lappert, M. F.; Rowe, R. S. Coord. Chem. Rev. 1990, 100, 267.
23. For other reviews dealing the chemistry of germylene and stannylene complexes see: (b) Petz, W. Chem. Rev. 1986, 86, 1019. (c) Holt, M. S.; Wilson, W. L.; Nelson, J. H. Chem. Rev. 1989, 89, 11. (d) For a very recent example of an insertion of a germanium amide into a Pt-H bond see: Litz, K. E.; Henderson, K.; Gourley, R. W.; Holl, M. M. Organometallics 1995, 14, 5008.
24. For other reviews dealing the chemistry of germylene and stannylene complexes see: (b) Petz, W. Chem. Rev. 1986, 86, 1019. (c) Holt, M. S.; Wilson, W. L.; Nelson, J. H. Chem. Rev. 1989, 89, 11. (d) For a very recent example of an insertion of a germanium amide into a Pt-H bond see: Litz, K. E.; Henderson, K.; Gourley, R. W.; Holl, M. M. Organometallics 1995, 14, 5008.
25. For other reviews dealing the chemistry of germylene and stannylene complexes see: (b) Petz, W. Chem. Rev. 1986, 86, 1019. (c) Holt, M. S.; Wilson, W. L.; Nelson, J. H. Chem. Rev. 1989, 89, 11. (d) For a very recent example of an insertion of a germanium amide into a Pt-H bond see: Litz, K. E.; Henderson, K.; Gourley, R. W.; Holl, M. M. Organometallics 1995, 14, 5008.
26. (a) Braunstein, P.; Knorr, M.; Villarroya, E.; DeCian, A.; Fischer, J. Organometallics 1991, 10, 3714.
27. (b) Knorr, M.; Braunstein, P.; Tiripiechio, A.; Ugozzoli, F. J. Organomet. Chem., in press.
28. Fontaine, X. L. R.; Jacobsen, G. B.; Shaw, B. L.: Thornton-Pett. M. J. Chem. Soc., Dalton Trans. 1988, 741.
29. Knorr, M. unpublished results, 1995.
30. (a) Blagg, A.; Cooper, G. R.; Pringle, P. G.; Robson, R.; Shaw, B. L. J. Chem. Soc., Chem. Commun. 1984, 933.
31. (b) Uson, R.; Formes, J.; Navarro, R.; Cebollada, J. I. J. Organomet. Chem. 1986, 304, 381.
32. (c) Witt, M.; Roesky, H. W. Chem. Rev. 1994, 94, 1163.
33. (d) Mague, T. J. J. Cluster Sci. 1995, 6, 217.
34. Burton, N. C.; Cardin, C. J.; Cardin, D. J.; Twamley, B.; Zubavichus, J. Organometallics 1995, 14, 5708.
35. ( 10) (a) Hitchcock, P. B.; Lappert, M. F.; Misra, M. C. J. Chem. Soc., Chem. Commun. 1985, 863.
36. (b) Campbell, G.; Hitchcock, P. B.; Lappert, M. F.; Misra, M. C. J. Organomet. Chem. 1985, 289, C1.
37. (c) Bushnell, G. W.; Eadie, D. T.; Pidcock, A.; Sam, A. R.; Holmes-Smith, R. D.; Stobart, S. R.; Brennan, E. T.; Cameron, T. S. J. Am. Chem. Soc. 1982, 104, 5837.
38. (d) Cardin, C. J.; Cardin, D. J.; Lawless, G. A.; Power, J. M.; Hursthouse, M. B. J. Organomet. Chem. 1987, 325, 203.
39. Braunstein, P.; Knorr, M.; Strampfer, M.; Tiripicchio, A.; Ugozzoli, F. Organometallics 1994, 13, 3038.
40. (a) Liehr. G.; Szucsanyi, G.; Ellermann, J. J. Organomet. Chem. 1984, 265, 95.
41. (b) Steil, P.; Nagel, U.; Beck, W. J. Organomet. Chem. 1989, 366, 313.
42. (a) Koe, J.; Tobita, H.; Ogino, H. Organometallics 1992, 11, 2479.
43. (b) For a very recent example of a mononuclear tungsten silyl germylene see: Figge, L. K.; Carroll, P. J.; Berry, D. H. Organometallics 1996, 15, 209.