An Ambient Self-Curable Latex Based on Colloidal Dispersions in Water of Two Functionalized Polymers and the Thermally Reversible Crosslinked Films Generated

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 39, Issue 3, 2001, Pages 389-397

  Ruckenstein, Eli ^a   Chen, Xiaonong ^a  

^a the State University of New York   (United States)

Author keywords

Ambient self curable latex; Amino functionalized polymer; Chlorine functionalized polymer; Dequaternization; Film formation; Latex blend; Quaternization; Thermally reversible crosslinking

Indexed keywords

EID: 0010807144     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0518(20010201)39:3<389::AID-POLA1006>3.0.CO;2-J     Document Type: Article

References (13)

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11. As shown in Table I, the mole content (5.5%) of the functional monomeric unit (DMAEA) in the PBN-1 particles, which was determined by separating the particles from the water phase of the polymer emulsion, was much lower than that in the feed (DMAEA/BA (mol/mol) = 8.6/100), indicating the existence of water-soluble DMAEA-rich polymer in the aqueous phase of the emulsion, which could not be separated from water together with the particles.
12. Pouchert, C. J. In The Aldrich Library of NMR Spectra, 2nd ed.; Aldrich Chemical Company: Milwaukee, 1983; Vol.1, 798, p B.
13. Deformation of a separated particle might also occur after drying due to the high flexibility of the BA copolymers, resulting in nonspherical shapes.