Synthesis and Crystal Structure of a Four-Metal Ketenylidene: [PPN]2[Fe3CuI(CO)9(CCO)]

Journal of the American Chemical Society

Volumn 113, Issue 4, 1991, Pages 1458-1460

  Gunale, Anuradha S ^a   Jensen, Michael P ^a   Stern, Charlotte L ^a   Shriver, Duward F ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0010778295     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00004a082     Document Type: Article

References (27)

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13. Anal. Calcd for Fe3CuIC84O10P4N2H62Cl2: Fe, 9.25; Cu, 3.51; C., 55.67; H, 3.45. Found: Fe, 9.16; Cu, 3.78; C, 53.95; H, 3.54.
14. Crystal data for [PPN]2(Te3CuI(CO)9(CCO)]: a = 1 1.863 (2) Å, b = 14.248 (4) Å, c = 23.807 (2) Å, α = 75.33 (2)°, β = 87.36 (1)°, y = 88.02 (2)°, K= 3888 (2) Å3, space group ####, Z = 2, dcalcd = 1.548 g/cm3, μ = 14.21 cm−1, Mo radiation, λ = 0.71073 Å, 7467 reflections with I > 2.58σI, RF = 0.038 and RwF = 0.042.
15. Davis, J. H.; Beno, M. A.; Williams, J. M.; Zimmie, J.; Tachikawa, M.; Muetterties, E. M. Proc. Natl. Acad. Sci. U.S.A. 1981, 78, 668.
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27. Anal. Calcd for Ru3CuIC84O10H62N2P4Cl2: Ru, 15.57; Cu, 3.29; C, 51.80; H, 3.21. Found: Ru, 16.31; Cu, 3.25; C, 53.04; H, 3.38.