The sphericity concept for an orbit of bonds. Formulation of chirogenic sites in a homospheric orbit and of bond-differentiating chiral reactions with applications to C60-adducts

Journal of Chemical Information and Computer Sciences

Volumn 36, Issue 2, 1996, Pages 270-285

  Fujita, Shinsaku ^a  

^a FUJIFILM CORPORATION   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0010721356     PISSN: 00952338     EISSN: None     Source Type: Journal    
DOI: 10.1021/ci950112n     Document Type: Article

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56. A proligand pair can be regarded as a proligand in an abstract fashion. From this standpoint, such a proligand is reversely considered to have an inner structure. This is an alternative way to treat higher relationships.
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59. l)-orbit in 16. Although the locativity terms are convenient to communicate stereochemical relationships, elaborate consideration should be based on the sphericity concept to avoid undesired confusion.
60. s)-orbits. Since they are energetically different from each other, the decarboxylation is a chemoselective achiral process.
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