Kinetic Resolution of Eucarvone Tricarbonyliron Complex with Sparteine-N-oxides

Synlett

Volumn 1997, Issue 3, 1997, Pages 287-288

  Petrowitsch, Tanja ^a   Eilbracht, Peter ^a  

^a TU DORTMUND UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0010469897     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1997-757     Document Type: Article

References (29)

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13. 9.
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19. D= -2.3 (c =1, methanol)
20. 3+].
21. 3). The latter value is confirmed by separation of 2 to the enantiomers by HPLC using KBD 4644 A (Bayer AG) with n-heptane/THF (3:1) leading to identical optical rotation values.
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29. This assignment is confirmed by an X-ray crystal structure of (2S)-(+)-2: T. Petrowitsch, R. Grosser, M. Schürmann, H. Preut, P. Eilbracht, Acta Cryst. C, manuscript in preparation.