Using two dimensional NMR techniques to assign proton and carbon spectra for cobalt(III) complexes derived from linear quinquedentate ligands containing nitrogen and sulfur donor atoms

Journal of Coordination Chemistry

Volumn 43, Issue 2-3, 1998, Pages 143-157

  Mcclure, Mark ^a   Worrell, Jay ^a  

^a UNIVERSITY OF SOUTH FLORIDA   (United States)

Author keywords

2 D NMR; Carbon spectrum; Cobalt(III); Proton spectrum; Quinquedentate; Structure

Indexed keywords

EID: 0010003819     PISSN: 00958972     EISSN: None     Source Type: Journal    
DOI: 10.1080/00958979808022663     Document Type: Article

References (26)

1. T. Jackman and J. Worrell, J. Inorg. and Nucl. Chem., 39, 981 (1977).
2. J. Worrell and T. Jackman, Inorg. Chem., 17, 3358 (1978).
3. J. Worrell, P. Behnken and R. Goddard, J. Coord. Chem., 9, 53 (1979).
4. T. Li, J. Breen and J. Worrell, J. Coord. Chem., 26, 15 (1992).
5. P. Coleman, J. Legg and J. Steele, Inorg. Chem., 9, 937 (1970).
6. Y. Yamomoto, H. Kudo and E. Toyota, Bull. Chem. Soc. Jpn., 56, 1051 (1983).
7. Y. Yamamoto, E. Toyota and Y. Yamamoto, Bull. Chem. Soc. of Jpn., 56, 2721 (1983).
8. K. Yamanari, N. Takeshita and Y. Shimura, Bull. Chem. Soc. Jpn., 57, 1227 (1984).
9. K. Yamanari, N. Takeshita and Y. Shimura, Bull. Chem. Soc. Jpn., 57, 2852 (1984).
10. R. Fenton, R. Vaff, P. Jones and P. Williams, Inorg. Chim. Acta., 128, 219 (1987).
11. E. Toyota, Y. Yamamoto and Y. Yamomoto, Bull. Chem. Soc. Jpn., 61, 3175 (1988).
12. J. Mandel, C. Maricondi and B. Douglas, Inorg. Chem., 27, 2990 (1988).
13. Y. Yamamoto, E. Toyota and S. Shimokawa, Bull. Chem. Soc. Jpn., 62, 2717 (1989).
14. P. Toscano, K. Belsky, T. Hsieh, T. Nicholson and J. Zubieta, Polyhedron, 10, 997 (1991).
15. P. Toscano, K. Belsky, T. Hsieh, T. Nicholson and J. Zubieta, Inorg. Chim. Acta., 206, 77 (1993).
16. A. E. Derome, Modern NMR Techniques for Chemistry Research, Pergamon Press, 1987.
17. J. Sanders and B. Hunter, Modem NMR Spectroscopy, A Guide for Chemists, 2nd edition. Oxford University Press, 1993).
18. G. Martin and A. Zektzer, Two-Dimensional NMR Methods for Establishing Molecular Connectivity: A Chemist's Guide to Experiment Selection, Performance, and Interpretation. VCH Publishers, 1988.
19. W. Croasmun and R. Carlson, Ed., Two-Dimensional NMR Spectroscopy: Applications for Chemists and Biochemists. VCH Publishers, 1994.
20. Distortionless Enhancement by Polarization Transfer: A DEPT spectrum phases methylene carbon opposite to methyl and methine carbon as referenced to the methylene carbon of an internal standard.
21. Correlated Spectroscopy: A COSY spectrum is a two-dimensional experiment used to detect connectivities (coupling) between sets of protons. Phase sensitive COSY distinguishes between active and passive coupling. Long-range COSY can be used to distinguish coupling that occurs between protons separated by up to four bonds.
22. Heteronuclear Correlation: HETCOR is a two dimensional experiment used to establish protoncarbon connectivities.
23. Willard, Merritt, Dean and Settle, Instrumental Methods of Analysis, 7th edition, Wadsworth Publishers, 1988.
24. S. Massoud and R. Milburn, Inorg. Chim. Acta., 154, 115 (1988).
25. S. Massoud and R. Milbum, Polyhedron, 8, 2389 (1989).
26. Nuclear Overhauser Enhancement Spectroscopy: NOESY is a two-dimensional experiment used to detect through-space coupling between nuclei.