Temperature dependence study of several polarity scales used in gas-liquid chromatography stationary phase characterization

Journal of Chromatographic Science

Volumn 37, Issue 4, 1999, Pages 113-120

  Santiuste, José M ^a   Takács, József M ^b  

^a INSTITUTO DE QUÍMICA FÍSICA ROCASOLANO   (Spain)

^b Gas Chromatographic Research Group for Study of Retention Index Systems Budapest   (Hungary)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0009787269     PISSN: 00219665     EISSN: None     Source Type: Journal    
DOI: 10.1093/chromsci/37.4.113     Document Type: Article

References (25)

1. J.M. Santiuste and J.M. Takács. Substance-specific and average polarity factors for characterization of stationary phases used in gas-liquid chromatography. J. Chromatogr. Sci. 35: 495-501 (1997).
2. Z. Szentirmai, G. Tarján, and J.M. Takács. Contribution to the theory of the retention index system. V. Characterization of polarity of stationary phases. McReynolds system. J. Chromatogr. 76: 11-18 (1972).
3. E. Kováts. Gas Chromatographic characterization of organic compounds. I. Retention indices for aliphatic halides, alcohols, aldehydes and ketones. Helv. Chim. Acta 41: 1915-32 (1958).
4. L.J. Rohrschneider. A method of characterization of gas chromatographic stationary phases. J. Chromatogr. 22: 6-22 (1966).
5. W.O. McReynolds. Characterization of some liquid phases. J. Chromatogr. Sci. 8: 685-91 (1970).
6. G.A. Huber and E. Kováts. Standard stationary phases. Anal. Chem. 45: 1155-63(1973).
7. C.F. Poole, R.M. Pomaville, and T.A. Dean. Proposed substitution of Apolane-87 of Squalane as a nonpolar reference phase in gas chromatography. Anal. Chim. Acta 225: 193-203 (1989).
8. J.M. Santiuste. The use of Kováts coefficients in gas chromatography and classification of 200 non-McReynolds stationary phases. An. Quím. 90: 315-23 (1994) (in Spanish).
9. E.R. Lombosi, T. Bernáth, and T.S. Lombosi. Data to the application of the Meisel-equation in GLC. Correction of the code-system and precalculation of the retention data in: "A survey". Twenty-Fifth Anniversary of the Foundation of Gas Chromatographic Research Group for Study of the Retention Index Systems, J.M. Takács, Ed. CRC, Budapest, Hungary, 1996, Chapter 8.
10. G. Tarján, S. Nyiredy, M. Gijor, E.R. Lombosi, T.S. Lombosi, M.V. Budahegyi, S.Y. Mészarós, and J.M. Takács. Thirtieth anniversary of the retention index according to Kováts in gas-liquid chromatography. J. Chromatogr. 472: 1-92 (1989).
11. J.M. Takács. Contribution to the retention index system in gas-liquid chromatography. J. Chromatogr. Sci. 29: 382-89 (1991).
12. J.M. Santiuste. Molecular structural coefficients of Takács. Their dependence on column temperature, stationary phase polarity and solute chemical nature. Chromatographia 38: 701-708 (1994).
13. J.M. Santiuste. Prediction of specific retention volume in gas chromatography by using Kováts and molecular structural coefficients. J. Chromatogr. A 690: 177-86 (1995).
14. J.A. García Domínguez, J.M. Santiuste, and Q. Dai. Gibbs energy of solution and molecular structural coefficients of 85 solutes on 20 gas chromatographic stationary phases. J. Chromatogr. A 787: 145-59 (1997).
15. J.M. Takács. Unified system for the prediction of retention data in gasliquid chromatography. J. Chromatogr. A 799: 185-205 (1998).
16. Q. Dai, J.A. García Domínguez, and J.M. Santiuste. New polarity scales for GLC stationary phases characterization. Chem. Anal. (Warsaw) 42: 329-44 (1997).
17. J.M. Santiuste. Unpublished results.
18. J.M. Santiuste and J.M. Taḱcs. Normalized partial molar Gibbs solution energy for twenty one GLC stationary phases and its temperature dependence over the 333-498K range. Models Chem. 134: 407-427 (1997).
19. J.M. Santiuste, Q. Dai, and J.M. Takács. Thermodynamic characterization of 100 solutes on 33 GC stationary phases. Solute-solvent interactions study in terms of structural parameters and equivalences with the modern solvation energy models. Models Chem. 135: 183-206 (1998).
20. Q. Dai. Ph. D. Thesis. Madrid. Universidad Autónoma. Spain (1996).
21. Q. Dai, R. Lebrón Aguilar, E. Fernández Sánchez, J.A. García Domínguez, and J.E. Quintanilla López. The effect of the trifluoropropyl group in polysiloxane stationary phases used for capillary gas chromatography. J. High Resolut. Chromatogr. 16: 721-24 (1993).
22. M.R. Becerra, E. Fernández Sánchez, A. Fernández Torres, J.A. García Domínguez, and J.M. Santiuste. Thermodynamic characteri-zation by inverse gas chromatography of a 50% methyl, 50% trifluoropropyl polysiloxanes. Macromolecules 25: 4665-70 (1992).
23. K. Grob. Making and Manipulating Capillary Columns for Gas Chromatography. Hüthig, Heidelberg, Germany, 1986.
24. L. Blomberg, J. Buitjen, K.E. Markides, and T. Wannman. Peroxideinitiated in situ curing of silicone gums for capillary column gas chromatography. J. Chromatogr. 239: 51-60 (1982).
25. E. Fernández Sánchez, A. Fernández Torres, J.A. García Domínguez, and J.M. Santiuste. Kováts coefficients for predicting polarities in silicone stationary phases and their mixtures. Chromatographia 31: 75-79(1991).