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Volumn 20, Issue 11, 1981, Pages 934-955

Transition Metal Thiometalates: Properties and Significance in Complex and Bioinorganic Chemistry

Author keywords

Bioinorganic chemistry; Molybdenum; Thiometalates

Indexed keywords

BIOCHEMICAL ENGINEERING; CATALYSIS; CHEMICAL REACTIONS - REDOX; SULFUR COMPOUNDS - MICROSTRUCTURE;

EID: 0009713281     PISSN: 05700833     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.198109341     Document Type: Review
Times cited : (764)

References (297)
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    • cf. also [114].
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    • 2O is also very weakly coordinated to the central W atom (A. Müller, M. Dartmann, unpublished results).
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    • Complete structure:, Z. Naturforschn in press.; P1; a = 9.130(l), b = 10.601(2), c = 13.339(2) Å; α = 87.11(1), β = 85.18(1), γ = 83.67(1)°; R = 0.76; preparation by the solid state reaction given in [123] and heating in CH3NO2; this avoids contamination by partial formation of W3OS 82−.
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    • unpublished work; the bond lengths given by F. Sécheresse show that in the crystal S has been partly replaced by O.
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    • 4−nS n2−) can be detected by recording the NIR/UV/VIS‐spectra and the cyclic voltammogram; A. Müller, R. Jostes, unpublished results.
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    • 2], and were isolated in pure form with discrete complex anions; the possible relevance to the nitrogenase problem was pointed out for the first time. Moreover, the strong M′ → MS 42− electron delocalization was pointed out, which explains for example the tendency of the Fe and Co complexes to accept more ligands
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    • Diploma thesis, Göttingen 1971. (The UV/VIS spectrum of [Fe, MoS4)2]3− is pictured, but no assignments could be made.
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    • 3− present in equilibrium does not precipitate as a PPh 4+ salt.
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    • In contrast to the case of binuclear and trinuclear complexes (see Section 5.1 and [155]), the complicated structures of type (a) and (b) compounds cannot be predicted spectroscopically.
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    • 3O[172]. However, a separation is possible in all cases.
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    • unpublished results. However, no clearly interpretable spectrum with Co hyperfine structure has yet been obtained.
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    • 2O, in which no redox processes were taken into account, are completely correct
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    • + salt [212] the crystal structure determination will be published in detail [120].
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    • 4), having the same structure as the corresponding S analogue, could also be isdated (A. Müller, J. Schirnanski, unpublished results).
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    • 3− could also be isolated crystalline solid by us.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.