Sequential dehydrogenation of unsaturated cyclic C5 and C5 hydrocarbons on Pt(111)

Journal of Physical Chemistry B

Volumn 102, Issue 50, 1998, Pages 10295-10306

  Manner, William L ^a   Girolami, Gregory S ^a   Nuzzo, Ralph G ^a  

^a University of Illinois at Urbana Champaign   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0009704647     PISSN: 10895647     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (78)

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69. The higher-frequency C - H bend seen in Figure 7 is weaker at lower coverges; this may explain why (other than because of the larger noise levels) this feature is not observable for the benzene generated from 1,4-cyclohexadiene, because the spectrum was obtained by dosing at low temperatures and then warming to 350 K. For 1,3-cylobexadiene, the spectrum shown had a higher benzene coverage because the surface was dosed at 350 K until a saturated overlayer was generated.
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78. 2 group that interacts with the surface (See Hostetler, M. J.; Nuzzo, R. G.; Girolami, G. S. J. Am. Chem. Soc. 1995, 117, 1814-1827). With the data now available, we know that this uncharacteristically high-frequwncy band is more properly assigned to the distal C-H strethes of the surface-contacting methylene units. An identical band is seen for cyclohexene.