A Short Pb⋯Pb Separation in the Polymeric Compound Bis(pyrrolidinecarbodithioato)lead(II) and a Conformational Pathway Interconversion for the "PbIIS4" Framework

Inorganic Chemistry

Volumn 36, Issue 17, 1997, Pages 3609-3615

  Caruso, Francesco ^a   Chan, Mei Ling ^b   Rossi, Miriam ^b  

^a CNR   (Italy)

^b VASSAR COLLEGE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0009504981     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic970059f     Document Type: Article

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45. 40 Reference 39 has a pentagonal bipyramidal electronic geometry with the Pb lone pair occupying an equatorial position; it is not octahedral. Reference 40 is a tetramer that shows two 5-coordinat Pb atoms with a bridging carbamate linking the two metal centers Both compounds do not fit the trend shown in Figure 3.