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The reduction of triphenylmethyl radical under reversible conditions has been recorded at -0.83 V relative to a silver perchlorate electrode, which in turn has a potential of +0.32 V vs. a saturated calomel electrode The calculated value for the reverse process of oxidation of triphenylmethide ion (relative to the standard hydrogen electrode) is +0.18 V. The corresponding value for the oxidation of the anion of triphenylcyclopropene is +0.91 V
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The reduction of triphenylmethyl radical under reversible conditions has been recorded at -0.83 V relative to a silver perchlorate electrode, which in turn has a potential of +0.32 V vs. a saturated calomel electrode (R. Breslow and K. Balasubramanian, J. Amer. Chem. Soc., 91, 5182 (1969)). The calculated value for the reverse process of oxidation of triphenylmethide ion (relative to the standard hydrogen electrode) is +0.18 V. The corresponding value for the oxidation of the anion of triphenylcyclopropene is +0.91 V.
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