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This work was presented in part at the 19th International Carbohydrate Symposium, San Diego, 1998; Abstract BP050.
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PCC or Swern oxidation proceeded with partial epimerization at C-4 (sugar numbering).
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44
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0041684038
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note
-
2-Aminothiazoline analogues of 2 can be readily obtained by reaction of 14 with an isothiocyanate followed by treatment of the corresponding thiourea with triflic anhydride and pyridine at low temperature (I. Storch de Gracia and J. L. Chiara, unpublished results).
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