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Volumn 69, Issue 17, 1997, Pages 3641-3645

Estimation of Free Radical Ionization Energies by the Kinetic Method and the Relationship between the Kinetic Method and the Hammett Equation

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EID: 0009022856     PISSN: 00032700     EISSN: None     Source Type: Journal    
DOI: 10.1021/ac970470k     Document Type: Article
Times cited : (12)

References (47)
  • 41
    • 85033147618 scopus 로고    scopus 로고
    • note
    • o is the rate of a reaction involving an unsubstituted compound k is the rate for the similar reaction involving a substituted compound, ρ is a reaction constant measuring the sensitivity of a reaction to the effects of electronic perturbation, its magnitude gives a measure of the degree to which the reaction responds to substituents, and σ is a substituent constant reflecting the nature of the substituent: electron-donating or -withdrawing.
  • 43
    • 0141491709 scopus 로고
    • H), the kinetic method parameter, represents the relative rates of dissociation from proton-bound dimers of substituted pyridines. All rates where χ represents the substituent are relative to pyridine. The data are taken from: McLuckey, S. A.; Cameron, D.; Cooks, R. G. J. Am. Chem. Soc. 1981, 103, 1313.
    • (1981) J. Am. Chem. Soc. , vol.103 , pp. 1313
    • McLuckey, S.A.1    Cameron, D.2    Cooks, R.G.3
  • 44
    • 85033127156 scopus 로고    scopus 로고
    • note
    • A linear correlation is observed for proton affinities of monosubstituted pyridine versus σ constant (r = 0.956).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.