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note
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o is the rate of a reaction involving an unsubstituted compound k is the rate for the similar reaction involving a substituted compound, ρ is a reaction constant measuring the sensitivity of a reaction to the effects of electronic perturbation, its magnitude gives a measure of the degree to which the reaction responds to substituents, and σ is a substituent constant reflecting the nature of the substituent: electron-donating or -withdrawing.
-
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43
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0141491709
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H), the kinetic method parameter, represents the relative rates of dissociation from proton-bound dimers of substituted pyridines. All rates where χ represents the substituent are relative to pyridine. The data are taken from: McLuckey, S. A.; Cameron, D.; Cooks, R. G. J. Am. Chem. Soc. 1981, 103, 1313.
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85033127156
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note
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A linear correlation is observed for proton affinities of monosubstituted pyridine versus σ constant (r = 0.956).
-
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45
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0141491709
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H) is taken from: McLuckey, S. A.; Cameron, D.; Cooks, R. G. J. Am. Chem. Soc. 1981, 103, 1313.
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