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3
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85036251097
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[formula presented] This should be accounted for with ancillary relations, for instance, the [formula presented] term, Eq. (14), to assure surface chemical equilibrium., Care must be taken in evaluating Eqs. (4567) since the equation pairs (45) and (67) are partial linear combinations. Direct simultaneous solution can erase the roles of [formula presented]
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Care must be taken in evaluating Eqs. (4567) since the equation pairs (45) and (67) are partial linear combinations. Direct simultaneous solution can erase the roles of Rrecomb(i) and Rdiss(i). This should be accounted for with ancillary relations, for instance, the K(i) term, Eq. (14), to assure surface chemical equilibrium.
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7
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0006942743
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edited by D. A. King, D. P. Woodruff, Elsevier, Amsterdam
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H. Wise B. J. Wood, in Advances in Atomic and Molecular Physics (Academic Press, New York, 1967), Vol. 3 pp. 291–253.
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85036412737
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The average transit, dissociation, and recombination times may be written, respectively: [formula presented]
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The average transit, dissociation, and recombination times may be written, respectively: τtrans≃Lcav/v, and τdiss(i)≃[1/νvibγdiss(i)]exp[ΔEdiss,act(i)/kT], and τrecomb(i)≃[2rAn(i,A)γrecomb(i)v(i,A)]-1.
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26
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85036387691
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Note, however, that bound species may be constrained to particular quantum states and geometric orientations on the surface, thereby affecting collision processes (affecting, for instance, the values of many parameters in Table II)
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Note, however, that bound species may be constrained to particular quantum states and geometric orientations on the surface, thereby affecting collision processes (affecting, for instance, the values of many parameters in Table II).
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